Tris-heteroleptic Iridium Complexes Based on Cyclometalated Ligands with Different Cores
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The optical gap of the organic semiconductor [1]benzothieno[3,2-b]benzothiophene and its 2,7-dibrominated analogue is measured in solution and in the crystalline state by means of UV-vis and emission spectroscopy. Bromination leads to a change in molecular ...
Over the past decade, lead halide perovskites (LHPs) have received considerable attention thanks to their impressive optoelectronic properties. Today, LHP-based devices are one of the most efficient single-junction solar cells, with power-conversion effici ...
Plasma wind tunnel experiments have been performed simulating a Hayabusa reentry trajectory point at 78.8km altitude with a velocity of 11.7km/s corresponding to a local mass-specific enthalpy of 68.4MJ/kg and a stagnation pressure of 2.44kPa. Ablation-rad ...
American Institute of Aeronautics and Astronautics2017
A detailed computational characterization of the one-photon absorption spectrum of a 2-((E)-2-[ 2,2']-bithiophenyl-5-yl-vinyl)-1-methyl-quinolinium cation in acetonitrile solution is presented. The main physico-chemical effects (solvation, vibronic progres ...
Detachment, an important mechanism for reducing target heat deposition, is achieved through reductions in power, particle and momentum; which are induced through plasma-atom and plasma-molecule interactions. Experimental research in how those reactions pre ...
Molecular spectroscopy is an essential experimental technique in both fundamental physical sciences and applied research. For example, electronic spectroscopy, in which light induces a change in the electronic state of a molecule, is a powerful tool for st ...
Yacora on the Web (www.yacora.de ) is a web application providing access to collisional radiative models based on the flexible solver Yacora. The main application range is plasma diagnostics in low-pressure plasmas. Available online are three collisional r ...
This thesis is devoted to the study of the optical properties of small metal clusters and metal cluster organic compounds. For this purpose a ultra-high vacuum (UHV) experimental apparatus has been built which allows for the deposition of mass selected neu ...
Vibrationally resolved spectra provide a stringent test of the accuracy of theoretical calculations. We combine the thawed Gaussian approximation (TGA) with an on-the-fly ab initio (OTF-AI) scheme to calculate the vibrationally resolved emission spectra of ...
We report seven heteroleptic cationic iridium(III) complexes with cyclometalating N-arylazoles and alkyl/aryl isocyanides, ((CN)-N-boolean AND)(2)Ir(CNR)(2), and characterize two of them by crystal structure analysis. The complexes are air- and m ...