On the Assessment of the CO2 Mitigation Potential of Woody Biomass

Woody biomass, a renewable energy resource, accumulates solar energy in form of carbon hydrates produced from atmospheric CO2 and H2O. It is, therefore, a means of CO2 mitigation for society as long as the biogenic carbon released to the atmosphere when delivering its energy content by oxidation can be accumulated again during growth of new woody biomass. Even when considering the complete life cycle, usually, only a small amount of fossil CO2 is emitted. However, woody biomass availability is limited by land requirement and, therefore, it is important to maximize its CO2 mitigation potential in the energy system. In this study, we consider woody biomass not only as a source of renewable energy but also as a source of carbon for seasonal storage of solar electricity. A first analysis is carried out based on the mitigation effect of woody biomass usage pathways, which is the avoided fossil CO2 emissions obtained by using one unit of woody biomass to provide energy services, as alternative to fossil fuels. Results show that woody biomass usage pathways can achieve up to 9.55 times the mitigation effect obtained through combustion of woody biomass, which is taken as a reference. Applying energy system modeling and multi-objective optimization techniques, the role of woody biomass technological choices in the energy transition is then analyzed at a country scale. The analysis is applied to Switzerland, demonstrating that the use of woody biomass in gasification–methanation systems, coupled with electrolysers and combined with an intensive deployment of PV panels and efficient technologies, could reduce the natural gas imports to zero. Electrolysers are used to boost synthetic natural gas production by hydrogen injection into the methanation reaction. The hydrogen used is produced when there is excess of solar electricity. The efficient technologies, such as heat pumps and battery electric vehicles, allow increasing the overall efficiency of the energy system while generating demand for the solar electricity.

Thermo-Economic Optimisation of Solar Tower Thermal Power Plants

James Spelling

Amidst a backdrop of rapidly increasing world-wide electricity demand, solar thermal power generation shows great potential for supplying the electricity needs of numerous countries in the Sun-belt regions of the world. In these regions, the absence of significant biomass, hydrological or geothermal reserves makes solar thermal power the most promising solution for meeting that most fundamental of demands: energy. Amidst the different options available for harnessing the Sun’s power, solar thermal technologies have been shown capable of producing electricity at the most economically viable rates [32]. However, all currently existing solar thermal power plants have been based around the use of Rankine, or steam turbine, cycles which are limited in the efficiencies they can achieve. In order to make better use of the Sun’s energy, higher efficiency cycles should be used. With their high concentration ratios, solar thermal power tower systems are amongst the best options for making use of the Sun’s potential. As the energy delivery temperature of central receiver systems is higher, they harness the solar radiation at a higher exergy level [4]. This higher temperature also opens the road to the use of more advanced thermodynamic cycles. Hybrid fossil-fuel – solar systems are also imaginable [13], as the energy delivery temperature is compatible with standard gas turbine cycles. Hybrid systems can help mitigate the requirements of thermal energy storage, as well as reducing the perceived risk when investing in new solar technology, which stimulates research and development, as well as providing employment. Recent developments in the field of high temperature volumetric receivers [10] along with rock- based packed-bed storage systems have opened up an interesting possibility. High temperature receivers allow the use of higher-efficiency combined-cycle setups, whereas packed-bed units offer the possibility of cheap storage. Larger storage volumes allow pure-solar systems to extend their power production into the night, making hybrid options less attractive. This is compounded by the common practice of guaranteeing a preferred tariff for electricity sales from pure-solar sources With this in mind, a complete dynamic model of a power plant based on the pure-solar concept has been elaborated. The performance of the setup is evaluated over a range of days, using solar insolation profiles obtained from satellite data. In order to examine different design options and their impact on the performance of the power plant, a multi-objective, thermo-economic optimisation of both the power plant superstructure and operating conditions was performed using the new, dynamic models. By means of an evolutionary algorithm [17], a family of Pareto-optimal points were obtained, representing the trade-off between increased power plant efficiency, and lower levelised energy costs. Through use of optimisation, it was shown that exergetic efficiencies in the region of 21-27% can be achieved, for relatively low power outputs of between 3 and 11 MWe. These configurations correspond with levelised electricity costs in the region of 14-21 UScts/kWhe. In most regions, the use of solar power is encouraged by the guarantee of a preferential tariff for electricity sales from renewable sources. Sale of electricity at a price of around 24 UScts/kWhe [32] should therefore be imaginable, ensuring the economic viability of solar thermal power tower systems. It can be concluded that, when properly designed, solar thermal power plants based on combined cycles are both economically and thermodynamically promising. By raising the efficiency of the plant, the size of the solar collector field is diminished, increasing the otherwise low energy densities of solar power systems. By reducing the levelised electricity costs, solar thermal power plants become more economically viable, accelerating their construction and thus, hopefully, reducing our dependence on fossil-fuels.

2009

Life Cycle Analysis and Thermo-Environomic Optimization of Concentrated Solar Thermal Power Plants

Aurélie Kuenlin

Confronted to resources depletion and the global warming, the humanity has to reduce its fossil fuels dependence. The renewable energy is an interesting option to reach this aim. The most powerful one is the solar energy since in few hours, the Earth receives more energy than the humanity consumes in one year. In order to convert this energy to electricity, the concentrated solar power plants (CSP) are more advantageous than photovoltaics (PV) because of the possibility to store the energy. Indeed, they concentrate with numerous mirrors the sunlight to heat up a ﬂuid which can be stored in a big insulated tank. Then, the heat energy is transferred to a steam which drives a turbine and a generator to produce electricity. Nowadays, this type of power plants has a real potential. The aim of this work is to test and conﬁrm that the CSP engender less environmental impacts than other types of power plants over their entire life cycle including production, operation and end of life. Furthermore, four different technologies of CSP (tower, parabolic trough, Fresnel and dish) are compared in order to ﬁnd the most efﬁcient one for the environment and identify their strong and weak points. Finally, multi-objectives optimizations, which consider economic and thermodynamic aspects, are performed to ﬁnd the optimal conﬁguration for each power plant. In this work, the environmental impacts are calculated by carrying out a life cycle analysis (LCA) with the Impact 2002+ method. It takes into account the damages on resources, climate change, human health and ecosystem quality. According to this study, the results indicate that CSP produce lightly less impacts than PV but much less impacts than fossil fuels energy. The comparisons between the different CSP reveal that the dish technology engenders less damages than other due to its high efﬁciency and less facilities. However, its investment costs are too important to be competitive. From the other hand, Fresnel and parabolic technologies produce too much environmental impacts for lower costs. The weak point of Fresnel is its very low efﬁciency and the disadvantage of parabolic is the use of a speciﬁc synthetic oil which is very harmful for the environment, without speaking of the possible spills. Moreover, the hybridation with natural gas of both technologies reduces their costs but increases considerably the impacts on climate change and resources categories. Finally, the tower technology is the most advantageous CSP regarding the impacts, the electricity production and costs. It does not need hybridation to have low costs and have an important storage capacity to produce electricity during nights and cloudy days. However, the investment is still too important to be more attractive than fossil fuel power plants. Therefore, there are two possibilities: to implement a CO2 tax of around 60$/MWh or to improve CSP technology. For the last option, the steel of the mirrors structure, which is the most harmful material according to LCA results, can be reduced and thus, the impacts and the costs will be lower. It can also be possible to use recycled steel or another material. Another hint is to build CSP in a very sunny regions with a DNI of at least 1750 kWh/m2 /yr with short transmission lines. Finally, it is important to increase as much as possible the efﬁciency of CSP to produce more energy and decrease the environmental impacts too.

2011

Coupling of electrocatalysts to photoabsorbers for solar fuels production

Carlos Gilberto Morales Guio

The direct transformation of sunlight into fuels and chemicals has attracted considerable attention for the potential impact on the storage of solar energies at large scales and the reduction of CO2 emissions. More than 80% of our current global energy consumption comes from the burning of non-renewable fossil fuels which produces enormous quantities of CO2 and contributes to global warming. We believe today that the key to reduce our dependence on exhaustible natural resources and limit the emission of greenhouse gases is the transition to CO2-free renewable energy sources. However, harvesting of energy from renewable sources (i.e. solar, wind, tidal) is intermittent and the deployment of devices for their transformation into useful forms of energy (i.e. electricity, chemicals, fuels, biomass) in a global scale is conditioned upon the improvement in efficiency of the energy storage mechanisms. A promising approach to store energy is the use of sunlight to drive the production of hydrogen fuel from water. Hydrogen produced from water and sunlight can be transformed back to electricity on demand or be used to generate mechanical energy in cars to power the transportation industry. The oxidation of hydrogen generates useable energy and at the same time exhaust clean, carbon-free water as the only product. Therefore, the production of hydrogen using a renewable energy source in an efficient and inexpensive device has the potential to discourage the continued use of fossil fuels and improve our environment. The viability of any mechanism for the storage of sunlight as fuel will depend on the reduction of energy penalties during the transformation process. Electrocatalysts are advanced materials that bring into one active site electrons and molecules in the appropriate orientation to lower activation energy barriers, accelerate rate of transformations and improve overall efficiencies for chemical reactions. The best catalysts for water splitting are precious metals such as Pt, Ir and Ru, which show superior rates of reaction at low overpotentials. However, these noble metals are too expensive and scarce for large scale applications. This thesis summarizes our recent research in the preparation, characterization, and application of Earth-abundant electrocatalysts for solar water splitting. Although in the last decade a great number of efficient and inexpensive electrocatalysts have been reported, methods for the deposition of these materials on the surface of photoabsorbers are rarely reported. This work shows various simple and scalable techniques for the deposition of hydrogen and oxygen evolving electrocatalysts on the surface of photocathodes and photoanodes, respectively. Surface-protected photocahodes were activated for solar hydrogen production in alkaline conditions with MoS2+x, Ni-Mo and Mo2C. A novel method for the deposition of an optically transparent amorphous iron nickel oxide oxygen evolution electrocatalyst is also reported. The catalyst was deposited on both thin film and high-aspect ratio nanostructured hematite photoanodes. The low catalyst loading combined with its high activity at low overpotential results in significant improvement on the onset potential for photoelectrochemical water oxidation. This transparent catalyst further enables the preparation of a stable hematite/perovskite solar cell tandem device, which performs unassisted water splitting.

EPFL2016