Characterizing the Effects of a “Switchable Water” Additive on the Aqueous Solubility of Small Molecules
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Several hydrophobic long-chain quaternary ammonium and phosphonium ionic liquids (ILs) with functionalized aromatic anions were prepared following a metathesis route using tricaprylmethylammonium chloride (Aliquat 336) and trihexyl(tetradecyl) phosphonium ...
Twelve Pt(II) complexes with cis-PtP2S2 pharmacophores (where P-2 refers to two monodentate or one bidentate phosphane ligand and S-2 is a dithiolato ligand) were prepared, characterized and evaluated as potential antiproliferative agents. The various comp ...
This paper deals with the definition and determination methods of the soil-water retention surface (SWRS), which is the tool used to present the hydromechanical behaviour of soils to highlight both the effect of suction on the change in water and total vol ...
An encapsulation device, designed on the basis of the laminar jet break-up technique, is characterized for cell immobilization with different types of alginate. The principle of operation of the completely sterilizable encapsulator, together with technique ...
Sonochemical elimination of organic pollutants can take place through two degradation pathways. Molecules with relatively large Henry’s law constants will be incinerated inside the cavitation bubble, while nonvolatile molecules with low Henry’s law constan ...
This Ph.D. work deals with the development of lanthanide-based bioprobes for biomedical analyses and imaging. For this purpose, two different approaches have been followed, one focusing on visible-emitting complexes, while the second addresses the sensitiz ...
Novel chemical compounds of the general formula KA, in which K is a 5- or 6- membered heterocyclic ring having 1-3 hetereo atoms, which can be independently N, S, or 0 with the proviso that at least one of the hetereo atoms must be a quaternized n ...
A simple approach to sensor development based on encapsulating a probe molecule in a cellulose support followed by regeneration from an ionic liquid solution is demonstrated here by the codissolution of cellulose and 1-(2-pyridylazo)-2- naphthol in 1-butyl ...
The soly. of H2S in a series of 1-butyl-3-methylimidazolium ([bmim]+) based ionic liqs. (ILs) with different anions, chloride, tetrafluoroborate ([BF4]-), hexafluorophosphate ([PF6]-), triflate ([TfO]-), and bis(trifluoromethyl)sulfonylimide ([Tf2N]-), and ...
The cyclic undecapeptide cyclosporin A (CsA) has a remarkable spectrum of diverse biological activities, including anti-inflammatory, antifungal, antiparasitic as well as immunosuppressive activities. However, the low water solubility of this drug is a ser ...