Fine particle pH and gas-particle phase partitioning of inorganic species in Pasadena, California, during the 2010 CalNex campaign
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A new method for the synthesis of industrially important azoimidazolium dyes is presented. The procedure is based on a reagent which is rarely used in the context of synthetic organic chemistry: nitrous oxide (“laughing gas”). N2O is first coupled to N-het ...
The hygroscopicity of an aerosol strongly influences its effects on climate and, for smaller particles, atmospheric lifetime. While many aerosol hygroscopicity measurements have been made at lower relative humidities (RH) and under cloud formation conditio ...
Volatility and hygroscopicity are two key properties of organic aerosol components, and both are strongly related to chemical identity. While the hygroscopicities of pure salts, di-carboxylic acids (DCA), and DCA salts are known, the hygroscopicity of inte ...
We present the development of ANISORROPIA, the discrete adjoint of the ISORROPIA thermodynamic equilibrium model that treats the Na +-SO 4 2- HSO 4 -NH 4 +-NO 3 -Cl -H 2O aerosol system, and we demonstrate its sensitivity analysis capabilities. ANISORROPIA ...
To explain the spa al and temporal distribu on of atmospheric aerosols over the southern US both biogenic vola le organic compounds (BVOC) and anthropogenic aerosols emissions should be taken into account. With the purpose of understanding their relationsh ...
Particle water and pH are predicted using meteorological observations (relative humidity (RH), temperature (T)), gas/particle composition, and thermodynamic modeling (ISORROPIA-II). A comprehensive uncertainty analysis is included, and the model is validat ...
Gas- and aerosol-phase measurements of oxidants, biogenic volatile organic compounds (BVOCs) and organic nitrates made during the Southern Oxidant and Aerosol Study (SOAS campaign, Summer 2013) in central Alabama show that a nitrate radical (NO3) reaction ...
Inorganic aerosol composition was measured in the southeastern United States, a region that exhibits high aerosol mass loading during the summer, as part of the 2013 Southern Oxidant and Aerosol Study (SOAS) campaign. Measurements using a Monitor for AeRos ...
Volatility-hygroscopicity tandem differential mobility analyzer measurements were used to infer the composition of sub-100nm diameter Southern Ocean marine aerosols at Cape Grim in November and December 2007. This study focuses on a short-lived high sea sp ...
Copper(II) is known to catalyze the generation of reactive nitrogen species in the presence of hydrogen peroxide, nitrite or nitric oxide, leading to tyrosine nitration, a biomarker for free radical species associated diseases. Here, we find that biologica ...