Features of proteolytic properties of tetraphenylporphyrin complex with lanthanide group metals
Publications associées (51)
Graph Chatbot
Chattez avec Graph Search
Posez n’importe quelle question sur les cours, conférences, exercices, recherches, actualités, etc. de l’EPFL ou essayez les exemples de questions ci-dessous.
AVERTISSEMENT : Le chatbot Graph n'est pas programmé pour fournir des réponses explicites ou catégoriques à vos questions. Il transforme plutôt vos questions en demandes API qui sont distribuées aux différents services informatiques officiellement administrés par l'EPFL. Son but est uniquement de collecter et de recommander des références pertinentes à des contenus que vous pouvez explorer pour vous aider à répondre à vos questions.
Two unsymmetrical ditopic hexadentate ligands designed for the simultaneous recognition of two different trivalent lanthanide ions have been synthesized, LAB2 and LAB3, where A represents a tridentate benzimidazole-pyridinebenzimidazole coordination unit, ...
Due to their high and variable coordination numbers leading to poorly predictable threedimensional coordination spheres, the trivalent lanthanide metal ions are challenging molecular objects for introduction into thermotropic liquid crystals. Conversely, t ...
The hexadentate bispidine-based ligand 2,4-bis(2-pyridyl)-3,7-bis(2-methylenepyridine)-3,7-diazabicyclo[3.3.1]nonane-9-on-1,5-bis(carbonic acid methyl ester), L-6m, with four pyridine and two tertiary amine donors, based on a very rigid diazaadamantane-der ...
Several washing agents ( EDTA, CDTA, NTA, 8 HQS, Ti-EDTA- citrate, Ca2+, and H+) were tested for their ability to extract adsorbed metal from biological surfaces to distinguish between internalized and total cellular metal (Pb, Ni, Cd, Zn, and Cu) for a gr ...
The nature of the bonding in ethylene and h2-P4 complexes, M(C2H4)2+ and M(h2-P4)2+, of group 11 metal cations (M = Cu, Ag, Au) has been explored by d. functional calcns. On the basis of the evaluation of symmetry orbitals, the contributions from the inter ...
The solid-state structure of the cationic MeO-Biphep Rh(I) compd. [Rh((S)-MeO-Biphep)(P{OMe}3)2]BF4 (3) was detd. by x-ray diffraction. The four P-donors deviate markedly from square-planar geometry, with the phosphite ligands P2 and P2' ca. +-0.61(7) .ANG ...
Reactions of tBuP(NH2)2 with Group 13 trialkyls MR3 (M = Al, Ga, In; R = Me, tBu) were investigated in detail. According to variable-temp. (VT) NMR investigations, the reaction proceeds stepwise with the initial formation of aminophosphane adducts, which s ...
Ruthenium-based anticancer chemotherapies are making significant advances in clinical trials. Until recently, the focus has been on coordination complexes, and mechanisms such as "activation by reduction" and "transferrin-targeted delivery" have been propo ...
The use of extn. techniques to alleviate product inhibition in bioprocesses is one of a no. of potential sepn. methods. However, the intimate contact of an org. phase with the broth implies that the org. components of this phase may be present in the aq. p ...
Four tetracatenar (L1–L4) and one hexacatenar (L5) ligands, derived from the diaza-18-crown-6 framework, are synthesized and characterized. In these ligands, the amine functions are fitted with benzoyloxybenzyl linker groups, attached either with a carbony ...