Combining ultra-high resolution ion-mobility spectrometry with cryogenic IR spectroscopy for the study of biomolecular ions
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This study explores the potential of MALDI-TOF MS for the mass measurement of large non-covalent protein complexes. The following non-covalent complexes have been investigated: aerolysin from Aeromonas hydrophila (335 kDa) and α-haemolysin from Staphylococ ...
Predissocn. spectra were detd. for SF6-Ar clusters in a mol. beam by monitoring the decrease in a specific mass spectrometer signals induced by a tunable continuous-wave CO2 laser. A red shift occurs downstream from the nozzle as the gas expands and the cl ...
Because the spectral d. of Rydberg states scales with the third power of the principal quantum no. n, the region immediately below at. and mol. ionization thresholds is spectrally very dense. Studying the properties of high at. and mol. Rydberg states just ...
"A high efficiency three-stage cyclotron has been proposed [1] to provide a 10 MW proton beam in the 1 GeV kinetic energy range for driving the Energy Amplifier. This accelerator complex consists of the following chain: two 15 MeV compact isochronous caylo ...
Aeromonas glycerophospholipid:cholesterol acyl transferase undergoes a conformational transition upon activation by treatment with trypsin. Chemical cross-linking and sedimentation velocity analysis showed that the lipase dimerizes due to removal of a regi ...
Two-dimensional (2D) Fourier transform ion cyclotron resonance (2D FT-ICR) allows one to obtain direct evidence for the occurrence of ion-mol. reactions. In 2D FT-ICR spectra, one observes resonances with 2 distinct frequency coordinates w1 and w2 that cor ...
The bacterial type VI secretion system (T6SS) is a macromolecular machine that injects effectors into prokaryotic and eukaryotic cells. The mode of action of the T6SS is similar to contractile phages: the contraction of a sheath structure pushes a tube top ...
A new mass spectrometer of the omegatron type has been designed and tested. This new device, which we have called the resotron, combines the extremely low permanent outgassing and pumping rates of the omegatron (less than 10-11 torr liter/sec. and 10-3 lit ...
