Catalytic valorization of the acetate fraction of biomass to aromatics and its integration into the carboxylate platform
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The uptake of cadmium (Cd) was analyzed for six different perennial plant species growing in a wooded pasture of the Swiss Jura Mountains, where the soils are geogenically enriched in Cd (4.58 mg.kg(-1) on average (n = 36); maximal value: 16.3 mg.kg(-1)). ...
The water-soluble ruthenium(II)–mTPPTS complex (mTPPTS= meta-trisulfonated triphenylphosphine) efficiently catalyzes the generation of hydrogen from formic acid in aqueous solution. This catalyst has been immobilized in a hydrophilic silica sup- port to fa ...
Widespread production of biomass-derived fuels and chemicals will require cost-effective processes for breaking down cellulose and hemicellulose into their constituent sugars. Here, we report laboratory-scale production of soluble carbohydrates from corn s ...
Reported is a new and efficient strategy for rapid construction of the chiral tetrahydropyrrolo[2,1-a]isoquinolin-3(2H)-one structure from unique tertiary enamide synthons. A Cu(OTf)2/chiral Pybox complex catalyzes the intramolecular enantioselective addit ...
We demonstrate an experimental approach for upgrading lignin that has been isolated from corn stover via biomass fractionation using c-valerolactone (GVL) as a solvent. This GVL-based approach can be used in parallel with lignin upgrading to produce solubl ...
Diminishing petroleum reserves, uncertainties in energy supplies, rising demand for transportation fuels, requirement for sustainable economic growth together with global warming and stringent environmental restrictions has promoted our society to explore ...
Different plant species, ecotypes, varieties or cultivars can be selected, tailored and harnessed for the remediation of polluted soils, sites and brownfields, as well as for the phytotreatment of domestic or industrial wastewater. Several approaches are p ...
An efficient method has been developed for the direct amidification of carboxylic acids via sulfinylamides preformed in situ by the reaction of pure amines with prop-2-ene-1-sulfinyl chloride. The method can be applied to aliphatic acids, including pivalic ...
This thesis proposes some contributions to the spatial modelling of species distributions and extreme values. Predictive models are increasingly used to model the distribution of species and to estimate the potential effects of global change on biodiversit ...
The local atomic structure around the central iron of the synthetic soluble analog of malarial pigment in acetic acid solution and with addition of chloroquine as found by X-ray absorption spectroscopy is reported. The special interest was drawn to the axi ...
