Reactions of aliphatic amines with ozone: Kinetics and mechanisms
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5-amino-6-methyl-2-benzimidazolone (AMBI), used in the manufacture of dyes, was characterised as a biorecalcitrant compound by means of different biodegradability tests. In order to enhance the biodegradability of this important pollutant, the application ...
The discovery, study, and implementation of the Co- and Mn-catalyzed hydrohydrazination and hydroazidation reactions of olefins are reported. These reactions are equiv. to direct hydroaminations of C-C double bonds with protected hydrazines or hydrazoic ac ...
This study focuses on the mineralization of 5-amino-6-methyl-2-benzimidazolone (AMBI), an important precursor in the industrial production of dyes, through an integrated Fe(III) photoassisted–biological system without addition of other electron acceptor th ...
The kinetics of the oxidn. of nitrite to nitrate by peroxynitrous acid at pH 5.2 is best described by the rate law kobs = kiso + k'[NO2-] + k''[NO2-]2, in which the peroxynitrous acid isomerization rate const. kiso = (1.10 +- 0.05) s-1, k' = (3.2 +- 0.1) M ...
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The electrochem. oxidn. of 3-methylpyridine (3-MP) at synthetic boron-doped diamond (BDD) thin film electrode was studied in acid media by cyclic voltammetry and bulk electrolysis. The results showed that in the potential region of water stability there ca ...
In this paper, we present case studies of oxidative transformations of contaminants by oxidants which are relevant in natural and in technical systems. These oxidants are reactive oxygen species (ROS), manganese(III,IV), iron(III), and molecular dioxygen ( ...
Electrochemistry can bring important contributions to current applications, such as organic synthesis or wastewater treatment. In an environmental context, electrochemical processes are interesting substitutes to the conventional wastewater treatment techn ...
Free hydroxyl radicals (free . OH), singlet oxygen (O-1(2)), or . OH produced by DNA-copper-hydroperoxo complexes are possible DNA-damaging reactive oxygen species (ROS) in the reaction system containing copper, catechol, and DNA. para-Chlorobenzoic acid ( ...