Model-assisted identification of solid oxide cell elementary processes by electrochemical impedance spectroscopy measurements
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Using petrol as a main source of energy, during the 20th century, has caused considerable amounts of damage among which are atmospheric pollution and global warming. At the same time, many geologists and economists expect that the discovery rate of new pet ...
In this thesis, the electrochemical promotion of lr and Rh based catalysts was studied for the complete combustion of ethylene and propylene. The study was performed by using two types of electrocatalytical cells: a classical, pellet type cell and a tubula ...
The use of microbalances to study gas-solid reactions at high temps. and normal pressure is often limited by fluctuations due to thermal convection in the reaction zone. The fluctuations depend on the pressure, the type of gas, the temp., and the geometry ...
The electrochem. promotion of the complete catalytic oxidn. of ethylene and toluene on RuO2Catalyst films deposited on Y2O3-stabilized-ZrO2 (YSZ) was studied at temps. 400 to 500 Deg. Anodic polarization (1.5 V), i.e. O2- supply from the YSZ support to the ...
Synthetic boron-doped diamond thin film is a new promising anode material. Because of its properties (high anodic stability under drastic conditions and wide potential window), it is widely investigated for numerous possible electrochemical applications su ...
Fuel Cells are electrochemical devices that are able to directly convert chemical energy to electrical energy, without any Carnot limitation. Hence, their energy efficiencies are relatively high. Among the various types of fuel cells, solid oxide fuel cell ...
Electro-oxidn. of platinum film electrode deposited on yttria-stabilized zirconia (YSZ) is examd. in situ using potential programmed voltammetry at 450 DegC in oxygen contg. atm. Under prolonged anodic oxidn. different sorts of oxidized species are formed ...
Polymer electrolyte and solid oxide are the two fuel cell types (PEFC, SOFC) under development in Switzerland. The very distinct operating temperatures of 80 °C (PEFC) and 800–950 °C (SOFC) impose fundamentally different requirements upon the nature of the ...
The energy redistribution processes in C60 trapped in low temp. rare gas solids have been studied using one- and two-color femtosecond pump-probe spectroscopy. The data show an ultrafast internal conversion process, followed by a slower electronic relaxati ...
This work contributes to the generalization of the Non-faradaic Electrochemical Modification of Catalytic Activity effect, known under the acronym NEMCA. This effect is observed for the first time over an oxide catalyst, namely IrO2 supported on yttria-sta ...