Synthesis of Organic Super-Electron-Donors by Reaction of Nitrous Oxide with N-Heterocyclic Olefins
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Reaction of RuCl3 with 1-[2-(1,4-cyclohexadiene-1-yl)alkyl]-3-methylimidazolium chloride (alkyl = Et, butyl) and 1-[2-(1,4-cyclohexadiene-1-yl)ethyl]-2,3-dimethylimidazolium chloride affords a series of dimeric ruthenium complexes of the type [RuCl2(η6-are ...
We study hydrogen in the Saha regime, within the physical picture in terms of a quantum proton-electron plasma. Long ago, Saha showed that, at sufficiently low densities and low temperatures, the system behaves almost as an ideal mixture made with hydrogen ...
Homo- and heterobimetallic complexes of the late transitions metals have been synthesized by metathesis reactions of the corresponding chloro-bridged dimers. These reactions have the advantage of being fast and giving rise to structurally defined products ...
EPFL2006
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The mechanisms leading to ionization of neutral gas by means of microwaves in the electron cyclotron range of frequencies in a simple toroidal plasma configuration are investigated in the TORPEX device (Fasoli A et al 2003 Bull. Am. Phys. Soc. 48 119). The ...
The collisional energy dependence of the cross section for the Penning ionization of C60 mols. by metastable neon atoms was measured in the 0.035-0.5 eV range in a crossed beam expt. The results show a decreasing trend (.apprx.20%) in the low-energy range ...
Ionization energies (IE) of [M + zH]z+ (z+) electrospray-produced polypeptides were detd. by electron ionization in a Penning cell of 4.7 and 9.4 .T Fourier transform mass spectrometers. For z = 1+ and substance P, the found IE value of 11.0+-0.4 eV is in ...
