A Fast and Selective Near-Infrared Fluorescent Sensor for Multicolor Imaging of Biological Nitroxyl (HNO)
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NOx is removed from gas by redn. with at. N in a plasma jet at 50-1000 M and 5000-6000 K. The NOx-contg. gas is injected into the plasma jet at 30 m/s resulting in the reaction NO + N = N2 + O. A high redn. degree of NOx is attained with no salt wastes. Th ...
The chemical and electrochemical promotion of highly dispersed nanofilm Rh catalysts (dispersion: about 10 %, film thickness: 40 nm) has been investigated for the first time. To this end Rh metal was sputter-deposited, either on a purely ionic conductor (8 ...
In this thesis, the synthesis and characterization of V2O5-nanostructures, as well as the gas sensing properties of V2O5-nanofibers and carbon nanotubes have been investigated. Various modifications of the nanowires have been successfully employed in order ...
A new strategy is introduced that permits covalent attachment of an organic chromophore to a polyoxometalate (POM) cluster. Two examples are reported that differ according to the nature of the anchoring group and the flexibility of the linker. Both POMs ar ...
Using a density functional approach, we determine the relative stability of various oxygen species in alpha -quartz. We considered interstitial species in the form of atomic and molecular oxygen, as well as network species, such as peroxyl and ozonyl link- ...
The mechanism of the oxygen redn. reaction (orr) was studied in alk. media at La0.6Ca0.4CoO3-activated carbon electrodes in a channel flow cell (CFC). The electrodes were made by depositing a mixt. of the perovskite (La0.6Ca0.4CoO3) powder as the catalyst, ...
Nitrous oxide is the third most important gas contributing to global warming and its concentration in the atmosphere is still on the rise. Nitric acid production represents the largest source of N2O in the chemical industry, with a total annual emission of ...
Scanning electrochemical microscopy (SECM) was used to monitor in situ hydrogen peroxide (H2O2) produced at a polarized water/1,2-dichloroethane (DCE) interface. The water/DCE interface was formed between a DCE droplet containing decamethylferrocene (DMFc) ...
The dynamics of N2O decompn. to gaseous nitrogen and oxygen over HZSM-5 catalysts with a low iron content (200 and 1000 ppm) was studied by the transient response. Method in the temp. range 523-653 K. The active catalysts were prepd. from HZSM-5 with Fe in ...