From structure to application: studies on adenine-, pyrene- and lanthanide-based metal-organic frameworks
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The reaction of hydrated lanthanide hexafluoroacetylacetonates, [Ln(hfa)(3)(H2O)(2)], with 1,4-disubstituted benzenes afforded a new series of one-dimensional coordination polymers Ln(hfa)(3)(Q), where Ln = Eu, Gd, Tb, and Lu and Q = 1,4-diacet ...
Reaction in water between rare earth ions (Ln ) Y, La-Tm, except Pm) and the sodium salt of terephthalic acid leads to a family of lanthanide-based coordination polymers of general formula [Ln2(C8H4O4)3(H2O)4]n with Ln ) La-Tm or Y. The isostructurality of ...
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The multicomponent reaction of diboronic acids with a catechol and a tripyridyl linker results in the formation trigonal prismatic cages. The cages feature six dative boron–nitrogen bonds as structure-directing elements. The size of the cages can be varied ...
The hydrothermal synthesis and structural characterization of the lanthanide silicate system [Na6Ln2Si12O30x H2O] (Ln=La3+, Sm3+, Eu3+, Gd3+, and Tb3+), named AV-21, has been reported. Structural elucidation of the Sm3+ analogue (isomorphous with the Eu3+, ...
A rational approach to the formation of pure heteropolymetallic lanthanide complexes that uses a two-step assembly strategy and exploits the different size requirements of the two metals included in the final structure is described. The investigation of th ...
Hybrid solids, made of chem. dissimilar components, have drawn much interest in advanced materials synthesis due to their structural versatility and multifunctional properties. For example, metal-org. frameworks (MOFs) have been extensively explored for th ...
