Quantification methods for chloride binding in Portland cement and limestone systems
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The modeling platform µic has been extended to study the hydration of cement based systems. It is shown that the hydration kinetics of alite can be described through the implementation of two mechanisms: a solution controlled dissolution (SCD) mechanism fo ...
Thermodynamic modeling is a versatile tool for predicting the chemical composition cement during the hydration of cement. The quality of the thermodynamic modeling depends directly on the quality and completeness of thermodynamic database used. One of the ...
Addition of fine limestone provides an excellent means to reduce the amount of clinker in cement. It is now well accepted that limestone partially reacts in cementitious systems with C3A to produce hemi- and monocarboaluminate phases and as a consequence m ...
Tricalcium aluminate (C3A) is one of the main constituents of Portland cement. Even though it represents less than 10% of the total composition, its strong reaction with water can lead to a rapid setting, called flash set. Gypsum is added to regulate this ...
Chloride ion is in part bound into ordinary Portland cement paste and modifies its mineralogy. To understand this a literature review of its impacts has been made and new experimental data were obtained. Phase pure preparations of Friedel's salt, Ca4Al2(Cl ...
An important microstructural aspect of the early hydration of Portland cement (K) is the formation of a shell of hydration products around cement grains. There is, at present, limited information on the mechanism of formation of the shell and of the chemis ...
Experimental work has been done to determine changes in the particle shape of portlandite grown in the presence of different ions. To quantify the experimentally observed changes in morphology a new analysis tool was developed, allowing the calculation of ...
High-performance concrete is sensitive to early-age cracking, mainly due to its rapidly-developing autogenous shrinkage. Autogenous shrinkage and internal relative humidity (RH) decrease are direct consequences of the emptying of capillary pores due to cem ...
The mechanisms behind the expansion of samples immersed in solutions containing sulfate ions have been controversial. Expansion is believed to originate in the formation of ettringite, but it is not possible to find any direct correlation between these two ...
Supplementary cementitious materials (SCM) are known to reduce or even stop expansion due to alkali silica reaction (ASR) in concretes with reactive aggregates. Studies indicate that the main reason for this is the decrease in alkalinity of the pore soluti ...