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Incorporation of Clathrochelate-Based Metalloligands in Metal-Organic Frameworks by Solvent-Assisted Ligand Exchange

Publications associées (33)

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Dinuclear clathrochelate complexes with pendent cyano groups as metalloligands

Rosario Scopelliti, Kay Severin, Henrik Moodysson Rønnow, Ivica Zivkovic, Philip Pattison, Bálint Náfrádi, Euro Solari, Giacomo Cecot, Mathieu Jérémie Marmier, José Luis Bila

Dinuclear clathrochelate complexes with two, three, four, or five cyano groups in the ligand periphery were prepared following two distinct synthetic strategies: (a) zinc(II)- or cobalt(II)-templated polycondensation reactions of CN-functionalized arylboro ...

Royal Society of Chemistry2016

The crystal structures of eight mono-methyl alkanes have been determined from single-crystal or high-resolution powder X-ray diffraction using synchrotron radiation. Mono-methyl alkanes can be found on the cuticles of insects and are believed to act as rec ...

Int Union Crystallography2015

Water Adsorption in Porous Metal-Organic Frameworks and Related Materials

Wendy Lee Queen

Three criteria for achieving high performing porous materials for water adsorption have been identified. These criteria deal with condensation pressure of water in the pores, uptake capacity, and recyclability and water stability of the material. Water ads ...

2014

'Seeing' Atoms: The Crystallographic Revolution

Dieter Schwarzenbach

Laue's experiment in 1912 of the diffraction of X-rays by crystals led to one of the most influential discoveries in the history of science: the first determinations of crystal structures, NaCl and diamond in particular, by W. L. Bragg in 1913. For the fir ...

Swiss Chemical Soc2014

Metal-organic frameworks with high stability have been pursued for many years due to the sustainability requirement for practical applications. However, researchers have had great difficulty synthesizing chemically ultra-stable, highly porous metal-organic ...

Nature Publishing Group2014

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Analysis of the CO2 adsorption properties of a well-known series of metal-organic frameworks M-2(dobdc) (dobdc(4-) = 2,5-dioxido-1,4-benzenedicarboxylate; M = Mg, Mn, Fe, Co, Ni, Cu, and Zn) is carried out in tandem with in situ structural studies to ident ...

Royal Soc Chemistry2014

In this work, a flexible metal-org. framework (MOF) (nickname BPene), [Ni'(L)Ni(CN)4]n (L=1,2-bis(4-pyridyl)-ethylene) that shows reversible structural transitions between low porosity and high porosity phases during the adsorption and desorption of CO2 ha ...

2013

Using a combination of single-crystal and powder X-ray diffraction measurements, we study temperature- and pressure-driven structural distortions in zinc(II) cyanide (Zn(CN)(2)) and cadmium(II) imidazolate (Cd(im)(2)), two molecular frameworks with the ant ...

Amer Chemical Soc2013

Preparation and characterization of multiwalled carbon nanotube/In2O3 composites

László Forró, Arnaud Magrez, Klara Hernadi

We have prepared multiwalled carbon nanotube (MWCNT)/In2O3 composites using a simple impregnation method. The precursor compound indium(III) chloride (InCl3) was used to cover the surface of MWCNTs and distilled water was used as solvent. The applied mass ...

Pergamon-Elsevier Science Ltd2013

We report the synthesis of atomically monodisperse thiol-protected silver nanoclusters Ag-44(SR)(30), (SR = 5-mercapto-2-nitrobenzoic acid) in which the product nanocluster is highly stable in contrast to previous preparation methods. The method is on ...

Royal Society of Chemistry2013