The effect of sodium hydroxide on Al uptake by calcium silicate hydrates (C S H)
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Calcium sulphoaluminate cements (CSA) with the main phase yeâelimite are a promising class of non-Portland cements which are gaining increasing interest from the cement industry. However, the hydration kinetics of CSA cements varies strongly, even for ce ...
The occurrence of cracking due to alkali silica reaction (ASR) affects the service life of concrete structures. The dissolution of silica-containing minerals within aggregates causes the formation of ASR products, which fill macroscopic cracks and cause th ...
EPFL2021
The replacement of clinker with supplementary cementitious materials (SCMs) is the most interesting solution to reduce the CO2 emissions from cement production. The abundant availability of clays, which have a sufficient amount of kaolinite content in Thai ...
Nuclear quantum effects (NQEs) cause the nuclei of light elements like hydrogen to delocalize, affecting numerous properties of water and aqueous solutions, such as hydrogen-bonding and proton transfer barriers. Here, we address the prototypical case of aq ...
Demetallation of metalloporphyrin molecules is one of the essential degradation reactions in photosynthesis. The effect of metalloporphyrin nature on removal of central metals from tetraphenylporphyrin complexes based on lanthanide group metals (Dy, Er, Lu ...
This paper evaluates feasibility of alkali activation to boost the reactivity and cementitious properties of recycled glass powder ( GP), when it is used in four different binary mixtures with ordinary Portland cement ( OPC), alkali activated slag or fly a ...
Mesostructured silver catalysts have shown a substantial rise in reaction selectivity for the conversion of CO2 into fuels with increasing thickness of ordered, inverse-opal films. The challenge lies in the optimization of the morphology to maximize the CO ...
Vast amounts of phosphogypsum (PG) which is a by-product of phosphorous acid production from apatite rock using sulphuric acid, are deposited in large piles at many locations worldwide. PG materials are added at rates of the order of megatonnes (Mt) per an ...
Paul Scherrer Institute, World Resources Forum2019
Ye'climitc (Ca4Al6O12SO4 or C(4)A(3)(S) over bar) is the main hydraulic mineral present in calcium sulfoaluminate cement (CSA). The hydration of ye'elimite is responsible for the early age cement properties. We identify 5 stages in the hydration of neat st ...
This thesis investigates the effect of different parameters such as Fe (III), D-gluconate and heterogeneous particles on the nucleation and growth of synthetic C-S-H by using the dropwise precipitation method. Firstly, the effect of Fe (III) on the synthet ...
