Design Rules to Fully Benefit From Bifaciality in Two-Terminal Perovskite/Silicon Tandem Solar Cells

The photovoltaics industry is adopting bifacial systems which offer improved energy harvesting compared to monofacial ones. This stems from the collection of light reflected by the surroundings on the rear side of the modules, leading to system-level gains typically ranging from 5% to 25%(rel). The question arises, however, whether this bifacial gain also applies to two-terminal (2T) tandem solar cells, since the series-connected subcells must generate equivalent currents to achieve an optimal performance. Using comprehensive simulations based on realistic device characteristics and typical meteorological data at different locations, we demonstrate that 2T tandem solar cells can indeed benefit from bifaciality provided that their design is tailored to this configuration. The top cell needs to absorb significantly more light than when designed for monofacial operation. In the geographical locations and system configurations simulated here, a broad performance optimum is found at a mismatch value of 6 mA center dot cm(-2) under front illumination, corresponding to a top cell generating similar to 23 mA center dot cm(-2) compared to similar to 17 mA center dot cm(-2) in the bottom one. With such specific design, bifacial tandems can yield up to 1.2 times the energy output of bifacial single-junction devices across a wide range of locations.

Self-tracking Solar Concentration

Volker Günter Zagolla

Solar concentration is intended to decrease the cost of expensive solar cell material by replacing the solar cell with a focusing optical system as the initial receiving aperture. This reduces the amount of solar cell material needed but adds the need of tracking to the entire system in order to keep the smaller solar cell at the focal spot. In state of the art concentrators, precise tracking (less than 1°) is needed in two directions to cover diurnal and seasonal variations. This adds to the cost of the system, diminishing the savings from the smaller solar cell, and consumes energy which in turn decreases the overall system efficiency. A self-tracking concentrator has the potential to increases the tolerances of the system (less precise tracking needed) and cover seasonal variations (only tracking in one dimension remains). Self-tracking makes use of the energy of the spectrum that is typically not utilized in PV, thus self-tracking does not consume an outside surplus of energy. During the thesis such a self-tracking system was developed. This thesis describes two concepts for the realization of a self-tracking concentrator, one of which is then developed into a working demonstration device with an angular acceptance of 32° (±16°). The work covers both the development of these two different mechanisms as well as an analysis of their performance as a single element and a discussion of their performance as part of a much larger device. The first concept, the micro-fluidic concentrator, uses vapor bubbles to efficiently couple light into a liquid waveguide (chapter 3), while the second concept, based on a phase change actuation uses the thermal expansion of paraffin wax to create a coupling feature at a waveguide (chapter 4). Based on the findings, the phase-change concentrator was then expanded into a self-tracking concentrator with a possible effective concentration of 10x (chapter 5). As a result this thesis shows the feasibility of a self-tracking concentrator and describes in detail the processes and techniques for its realization. Future work based on the designs presented in this thesis can optimize the concepts. Simulations show that a system based on this approach can achieve 150x effective concentration by scaling the system collecting area to reasonable dimensions (30 x 1 cm²). An optimized optical system can then also increase the acceptance angle of the self-tracking concentrator to the ±23° needed in order to cover seasonal variations. In addition, the presented concept is based on earth abundant, inexpensive materials, making it technologically and economically viable to extend it to much larger formats.

EPFL2015

Energy Yield and Electricity Management of Thin-Film and Crystalline Silicon Solar Cells

Yannick Samuel Riesen

In the case of high photovoltaic (PV) penetration into the electricity grid, the energy produced by a PV system that is effectively used (useful energy) depends on the energy yield and on how this energy is managed to avoid detrimental effects occurring at high PV injection, e.g. during the midday peak. The overall goal of this thesis is to provide guidelines for maximizing the useful energy of a PV system by quantifying losses incurred during operation at both the solar cell device and the system levels. Solar cells are usually optimized for the standard test conditions (STC). However, the conditions are generally different during operation. This work assesses how solar cell materials and designs can be optimized to maximize the energy yield for specific operating condition. We mainly focus on thin-film silicon solar cells because of their challenging metastable behavior. The temperature dependence of the performance of thin-film amorphous silicon (a-Si:H) and microcrystalline silicon solar cells is thus measured for different deposition parameters and cell designs. We observe that, by tuning the intrinsic layer thickness of a-Si:H cells, the cells with the best (STC) efficiency do not necessarily provide the highest energy output. We also explain the presence of a maximum in the value of the fill factor as a function of temperature. The temperature dependence study is then extended to thin-film silicon multi-junction, crystalline silicon heterojunction (SHJ) and other crystalline silicon solar cells. For thin-film silicon solar cells, spectral effects and degradation or recovery effects due to the metastable character of a-Si:H (due to the Staebler-Wronski effect) significantly impact the energy yield. Based on indoor and outdoor degradation/recovery experiments, we show that it is challenging to describe this metastability with a diode model. However, such a model with a current loss term and an additional temperature dependence for the saturation current and ideality factors accurately reproduces the current-voltage characteristics of a-Si:H solar cells over a wide range of irradiance levels and operating temperatures. On the system level, we model a PV system with local storage to evaluate several strategies to reduce the detrimental midday injection peaks. The impact of such measures on the useful energy is also investigated. We develop a simple control algorithm that minimizes the losses due to a feed-in limit and maximizes self-consumption without the need of a production forecast. We show that heat storage using a boiler or a heat pump performs as well as battery storage. In general, a feed-in limit reduces significantly peak injection but only a relatively small storage capacity is needed to reduce losses (due to this limit). Changes in tilt and orientation of modules also reduce losses resulting from feed-in limits and shrink the winter/summer production ratio by more than a factor of two. We also develop a statistical method that estimates - from loads measured every 15 min - when different electrical appliances in a household are commonly used. This model indicates that about 8% of the total load could be shifted easily to the midday period, thereby reducing the midday injection peak. Finally, we combine device and system aspects to show that varying cell technology (e.g. with different temperature response) has a limited but not negligible impact on system output.

EPFL2016

The effect of illumination on the formation of metal halide perovskite films

Antonio Abate, Taisuke Matsui, Jiyoun Seo, Ludmilla Steier, Wolfgang Richard Tress, Amita Ummadisingu

Optimizing the morphology of metal halide perovskite films is an important way to improve the performance of solar cells(1) when these materials are used as light harvesters(2), because film homogeneity is correlated with photovoltaic performance(3). Many device architectures and processing techniques have been explored with the aim of achieving high-performance devices(4), including single-step deposition(5), sequential deposition(6,7) and anti-solvent methods(1,8). Earlier studies have looked at the influence of reaction conditions on film quality(3), such as the concentration of the reactants9,10 and the reaction temperature(11). However, the precise mechanism of the reaction and the main factors that govern it are poorly understood. The consequent lack of control is the main reason for the large variability observed in perovskite morphology and the related solar-cell performance(2,3). Here we show that light has a strong influence on the rate of perovskite formation and on film morphology in both of the main deposition methods currently used: sequential deposition and the anti-solvent method. We study the reaction of a metal halide (lead iodide) with an organic compound (methylammonium iodide) using confocal laser scanning fluorescence microscopy and scanning electron microscopy. The lead iodide crystallizes before the intercalation of methylammonium iodide commences, producing the methylammonium lead iodide perovskite. We find that the formation of perovskite via such a sequential deposition is much accelerated by light. The influence of light on morphology is reflected in a doubling of solar-cell efficiency. Conversely, using the anti-solvent method to form methyl ammonium lead iodide perovskite in a single step from the same starting materials, we find that the best photovoltaic performance is obtained when films are produced in the dark. The discovery of light-activated crystallization not only identifies a previously unknown source of variability in opto-electronic properties, but also opens up new ways of tuning morphology and structuring perovskites for various applications.

Nature Publishing Group2017