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The solid-state Li-ion conductor Li7TaO6: A combined computational and experimental study

Publications associées (34)

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Modeling, understanding, and screening fast lithium-ion conductors for solid-state electrolytes

Leonid Kahle

The Li-ion batteries within the consumer electronics used in our everyday life suffer from well-known deficiencies due to the prevalent use of organic liquid electrolytes: the narrow electrochemical stability windows of the organic solvents used in these e ...

EPFL2019

Vanadium-oxygen cell for positive electrolyte discharge in dual-circuit vanadium redox flow battery

Hubert Girault, Justyna Piwek, Alberto Battistel, Christopher Raymond Dennison

The “dual-circuit redox flow battery” takes advantage of a conventional all-vanadium redox flow battery (VRFB) combined with a separated catalytic hydrogen evolution reactor. Depending on demand, the VRFB can be conventionally discharged or supply H2 by us ...

2019

Stability of aqueous electrolytes based on LiFSI and NaFSI

Corsin Battaglia, David Reber

Through a combination of bulk, interface, and interphase effects, water-in-salt electrolytes, employing a high salt concentration, offer a wider electrochemical stability window than traditional dilute aqueous electrolytes. Here we explore chemical stabili ...

2019

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All redox flow batteries suffer from low energy storage density in comparison with conventional Li-ion batteries. However, this issue can be mitigated by utilization of solid energy storage materials to enhance the energy storage capacity. In this paper we ...

2019

Coatings with tailored electronic and optical properties for advanced glazing

Olivia Valérie Charlotte Bouvard

Modern envelope glazing relies on nanoscale coatings to meet a range of specific needs. Low emissivity coatings can improve the thermal performance of glazing thanks to a thin metallic film. However, the conductive nature of this layer leads to an attenuat ...

EPFL2019

A mixed anion hydroborate/carba-hydroborate as a room temperature Na-ion solid electrolyte

Radovan Cerny, Matteo Brighi

The novel compound Na2-x(CB11H12)(x)(B12H12)(1-x) shows a fast ionic Na conductivity of 2 mS cm(-1) at room temperature, reaching the superionic regime above 333 K. A low activation energy of 314 meV, in a thermodynamically and electrochemically stable str ...

ELSEVIER SCIENCE BV2018

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Accurate models capable to predict the dynamic behavior and the State-of-Charge (SoC) of Battery Energy Storage Systems (BESSs) is a key aspect for the definition of model-based controls in electric vehicles and in power grid applications of these energy s ...

2017

Conductive framework of inverse opal structure for sulfur cathode in lithium-sulfur batteries

Hua Wu, Xiaopeng Huang, Lu Jin

As a promising cathode inheritor for lithium-ion batteries, the sulfur cathode exhibits very high theoretical volumetric capacity and energy density. In its practical applications, one has to solve the insulating properties of sulfur and the shuttle effect ...

Nature Publishing Group2016

The progressive integration of renewable energy sources such as wind turbines and photovoltaic pannels in the current electrical network, and the rise of the electrical mobility, provoke a change of paradigm in the sector of energy management. The increasi ...

EPFL2015

Structural, electrical and magnetic characterization of in-situ crystallized ZnO:Co thin films synthesized by reactive magnetron sputtering

Andreas Schueler

Zn1-xCoxO (0 < x < 0.146) conductive thin films have been deposited by reactive magnetron sputtering of metallic Zn and Co targets at high pressure and temperature. The structural properties have been investigated by using X-ray diffraction (XRD) and X-ray ...

Elsevier Science Sa2015