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Data-Driven Advancement of Homogeneous Nickel Catalyst Activity for Aryl Ether Cleavage
Publications associées (50)
An Overview of Heterogeneous Catalysts Based on Hypercrosslinked Polystyrene for the Synthesis and Transformation of Platform Chemicals Derived from Biomass
Platform chemicals, also known as chemical building blocks, are substances that serve as starting materials for the synthesis of various value-added products, which find a wide range of applications. These chemicals are the key ingredients for many fine an ...
Basel2023Separable Brønsted acidic imidazolium salts for polysaccharide hydrolysis in water
The current reliance on limited petrochemical resources and the resulting ecological outcomes have made the exploration of alternative chemical and energy feedstocks invaluable. As such, the development of sustainable processes with a less harmful total en ...
EPFL2023Hydro-processing of biomass using novel metal-organic framework (MOF)/polymer composite catalysts
Generating value, in the form of functional chemicals, from biomass is a critical need of today. It is expected that replacing petroleum with biomass as the source of many commodity and fine chemicals can lead the transition away from a fossil-fuel based e ...
EPFL2022Oxidation of organic micropollutant surrogate functional groups with peracetic acid activated by aqueous Co(II), Cu(II), or Ag(I) and geopolymer-supported Co(II)
Peracetic acid (PAA) in combination with transition metals has recently gained increasing attention for organic micropollutant abatement. In this study, aqueous Co(II), Cu(II), and Ag(I) were compared for their capacity to activate PAA. Co(II) outperformed ...
PERGAMON-ELSEVIER SCIENCE LTD2022In depth analysis of heterogeneous catalysts for the chemoenzymatic dynamic kinetic resolution of beta-amino esters
Kumar Varoon Agrawal, Cédric Karel J Van Goethem
The chemoenzymatic dynamic kinetic resolution of beta-amino esters is established after detailed evaluation of metal-based heterogeneous catalysts for racemization and enzyme catalysts for kinetic resolution. Several heterogeneous palladium catalysts prove ...
ROYAL SOC CHEMISTRY2022Active sites on copper-based catalysts for electrochemical CO2 reduction selectively to C2+ products
Electrochemical CO2 reduction (eCO2RR) towards value-added chemicals, powered by renewable electricity, is a promising technology for storing the intermittent renewable energy in the form of chemical bonds. Among the various products of eCO2RR, multi-carbo ...
EPFL2022OSCAR: an extensive repository of chemically and functionally diverse organocatalysts
Rubén Laplaza Solanas, Puck Elisabeth van Gerwen, Alberto Fabrizio, Sergio Vela Llausi, Simone Gallarati
The automated construction of datasets has become increasingly relevant in computational chemistry. While transition-metal catalysis has greatly benefitted from bottom-up or top-down strategies for the curation of organometallic complexes libraries, the fi ...
ROYAL SOC CHEMISTRY2022Well-Defined Copper-Based Nanocatalysts for Selective Electrochemical Reduction of CO2 to Ethylene and Ethanol
Raffaella Buonsanti, Ludovic Emile Frédy Zaza, Kevin Rossi
The electrochemical CO2 reduction reaction (CO2RR) holds the promise to revolutionize the chemical industry by producing value-added chemicals and fuels from CO2 and water while storing renewable energy. However, catalyst design still remains one of the ma ...
2022Atomic Level Insights of Non-Noble Metal Catalysts for the Oxygen Evolution Reaction
The conversion of intermittent renewable energy resources in the form of chemical bond, such as hydrogen production from electrochemical water splitting, is a promising way to satisfy the future global energy demand and address the environmental issues. Th ...
EPFL2021Mechanisms of the Heterogeneously Catalyzed Reaction of CO2 Hydrogenation on Transition Metal Surfaces
Renewable energy supply and energy storage in a closed materials cycle are the urgent global challenges of the 21st century. Carbon dioxide (CO2) hydrogenation over catalysts is a method to produce synthetic fuels from renewable energy in a CO2 neutral cyc ...
EPFL2020