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Structural and Dynamical Properties of Potassium Dodecahydro-monocarba-closo-dodecaborate: KCB11H12

Publications associées (78)

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High pressure induced spin state crossover in Sr2CaYCo4O10.5

Jonathan White

The layered cobaltite Sr2CaYCo4O10.5 with formal average cobalt oxidation state close to 3+ has been studied as functions of both temperature and pressure up to 4GPa by neutron powder diffraction (NPD). The crystal structure is shown to have tetragonal sym ...

Institute of Physics2015

Impact of Annealing on the Early Hydration of Tricalcium Silicate

Karen Scrivener, Marco Cantoni, Amélie Bazzoni

It was recently proposed that the induction period observed during the hydration of tricalcium silicate could be explained by the build-up of ions in solution. Due to the importance of defects in this mechanism, this work describes the effect of different ...

Wiley-Blackwell2014

Synthesis, crystal growth and physical properties of the frustrated spin ladder material BiCu2PO6

Shuang Wang

In recent years quantum antiferromagnets with an intrinsically disordered (“spin liquid”) ground state and an energy gap in the spin excitation spectrum have received a great deal of attention. In search for new experimental realizations of spin-ladder and ...

EPFL2013

High temperature transformations in a steel-TiCN cermet

Daniele Mari

The influence of the carbon content on the microstructure, phase transformation and hardness of an iron-based cermet is studied. The cermet is constituted by a high-alloyed steel as matrix, and TiCN particles (50 vol.%) as reinforcement. The material is pr ...

Elsevier Sci Ltd2013

Preparation and characterization of multiwalled carbon nanotube/In2O3 composites

László Forró, Arnaud Magrez, Klara Hernadi

We have prepared multiwalled carbon nanotube (MWCNT)/In2O3 composites using a simple impregnation method. The precursor compound indium(III) chloride (InCl3) was used to cover the surface of MWCNTs and distilled water was used as solvent. The applied mass ...

Pergamon-Elsevier Science Ltd2013

The Role of Ca(BH4)(2) Polymorphs

This study compares the structure and decomposition behaviors of theα,β, and γ polymorphs of Ca(BH 4) 2 for hydrogen storage. Samples with different polymorphic contents are characterized using powder X-ray diffraction and vibrational spectroscopy. Decompo ...

2012

Incommensurate magnetic order in TbTe 3

Joël Mesot

We report a neutron diffraction study of the magnetic phase transitions in the charge-density wave (CDW) TbTe 3 compound. We discover that in the paramagnetic phase there are strong 2D-like magnetic correlations, consistent with the pronounced anisotropy o ...

Institute of Physics2012

Mobility and dynamics in the complex hydrides LiAlH4 and LiBH4

Pascal Martelli

The dynamics and bonding of the complex hydrides LiBH4 and LiAlH4 have been investigated by vibrational spectroscopy. The combination of infrared, Raman, and inelastic neutron scattering (INS) spectroscopies on hydrided and deuterided samples reveals a com ...

2011

Chemical Developments in DNP-NMR

Pascal Miéville

The Nuclear Magnetic Resonance (NMR) is an extraordinary tool to understand molecular structures. Its main limitation resides in its relatively low sensitivity when compared with other physico-chemical methods such as Mass Spectrometry (MS) or Optical Spec ...

EPFL2011

Solid state transformations of Au-Cu-Pt alloys studied by in-situ X-ray synchrotron radiation and DSC

Andreas Mortensen, Frédéric Diologent, Edwina Klay

Seven alloys of the ternary Au-Cu-Pt system, containing 75 or 76.5 wt.% Au with 0-15 wt.% Pt and heat-treated to a fully ordered condition, are examined using in-situ synchrotron radiation to determine transformation temperatures and phases formed, and to ...

Elsevier2011