Atomic scale symmetry and polar nanoclusters in the paraelectric phase of ferroelectric materials
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The integration of ferroelectrics in electronic devices requires that they be used in the form of thin films, which implies that for such systems finite-size effects related to the presence of a ferroelectric-electrode interface become important. In this t ...
his thesis reports on the magnetic properties of bi- and tri-metallic nanostructures at surfaces. The main goal is to build the smallest nanostructure ferromagnetic at room temperature and the assembly of those structures in high density arrays. To this pu ...
An n=7 Aurivillius phase, Sr4Bi4Ti7O24, with c=6.44 nm, was synthesized as an epitaxial (001)-oriented film. This phase and its purity were confirmed by x-ray diffraction and transmission electron microscopy. The material is ferroelectric, with a P-r=5.3 m ...
The influence of the uniaxial bias stress on the piezoelectric properties of tetragonal BaTiO3 and PbTiO3 monodomain crystals is modeled in the framework of the phenomenological Landau-Ginzburg-Devonshire theory. It is shown that tensile and compressive st ...
Commercial glass frits (lead borosilicate glasses) were employed as the sintering aids to reduce the sintering temperatures of BST ceramics. The effects of the glass content and the sintering temperature on the microstructures, dielectric properties and tu ...
It is demonstrated that for classical perovskites, such as BaTiO3; SrTiO3, and PbTiO3, electrostrictive strain induced by an electric field may not obey traditionally considered "extension along the field and contraction perpendicular to it" behavior if th ...
It was noticed long time ago that the dielectric permittivity of BaTiO3 single crystals in the rhombohedral phase varies from observation to observation, but the microstructure mechanism behind this phenomenon remained unclear. We show that the variations ...
The temperature and pressure characteristics of a noncentrosymmetric crystal modification of NaNbO3 were studied by Raman spectroscopy. A transition towards the bulk-like structure of NaNbO3 occurs in the temperature range from 280 to 360 °C. High-pressure ...
Strontium barium niobate (SrxBa1-xNb2O6, shortly SBN) is a solid solution system with tetragonal tungsten bronze crystal structure. It exhibits a ferroelectric phase with only one polar axis and a transition temperature depending on the Sr/Ba ratio. This t ...
Ferroelectric perovskites exhibit superior dielectric, piezoelectric and ferroelectric properties. Architecting ferroelectrics in the small scale holds interest in both application and fundamental research. Compared to their 2D counterparts – thin films, f ...