Catalytic effects of photogenerated Fe(II) on the ligand-controlled dissolution of Iron(hydr)oxides by EDTA and DFOB
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The iron-catalyzed dehydrogenation of formic acid has been studied both experimentally and mechanistically. The most active catalysts were generated in situ from cationic Fe-II/Fe-III precursors and tris[2-(diphenylphosphino)ethyl]phosphine (1, PP3). In co ...
Harmful algal blooms in both freshwater and marine environments pose significant challenges for humans, livestock and aquatic food webs. Over the last 50 years, several authors proposed that small mol. iron chelators (siderophores) could be responsible for ...
In the aquatic environment and in engineered water treatment systems, organic contaminants can undergo oxidative and photochemical transformations. For an overall risk assessment, the toxicity of the resulting transformation products has to be investigated ...
Stable isotope ratios combined with elemental compositions and molecular biomass data provide a powerful tool in Neoproterozoic palaeoenvironmental interpretations. Here, we report the results of an extensive organic and inorganic geochemical study perform ...
Enzymic haem and non-haem high-valent iron-oxo species are known to activate strong C-H bonds, yet duplicating this reactivity in a synthetic system remains a formidable challenge. Although instability of the terminal iron-oxo moiety is perhaps the foremos ...
Biogenic influences on the composition and characteristics of aerosol were investigated on Bird Island (54°00' S, 38°03' W) in the South Atlantic during November and December 2010. This remote marine environment is characterised by large seabird and seal c ...
This chapter summarises the current knowledge on the vertical distribution of methane (CH4) and its formation in Lake Kivu. Additionally, we review the objectives and restrictions under consideration for sustainable extraction (safe, environmentally accept ...
The Neoproterozoic sedimentary successions of the Sierras Bayas Group (SBG) are situated within the Tandilia Belt, Buenos Aires Province, Argentina. The Loma Negra Formation (LNF) from the upper part of the SBG has been investigated using a combination of ...
Derivatives of dipicolinic acid with a polyoxyethylene pendant arm at the pyridine 4-position have been functionalized for potential grafting with biological material. Four ligands with different terminal functions (alcohol, methoxy, phtalimide and amine) ...
It is recognized that dissolved organic matter (DOM) plays an utmost role in aquatic ecosystems by binding trace metals and influencing their speciation, bioavailability and detrimental effects. DOM is considered to protect the aquatic microorganisms from ...
