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Elucidating the Doping Mechanism in Fluorene-Dithiophene-Based Hole Selective Layer Employing Ultrahydrophobic Ionic Liquid Dopant

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The understanding of mixed ionic-electronic conductivity in hybrid perovskites has enabled major advances in the development of optoelectronic devices based on this class of materials. While recent investigations revealed the potential of using dimensional ...

Royal Soc Chemistry2024

Thanks to the continuous improvement of crystalline silicon (c-Si) solar cells, largely dominating the market, photovoltaic electricity is nowadays the cheapest source of energy on the market. Yet, solar energy is far from being completely harvested, as t ...

EPFL2023

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Due to their strong acceptor properties and enhanced charge transport capabilities, non-fullerene electron acceptors based on pi-extended derivatives - subnaphthalocyanines (SubNc) or subphtalocyanine dimers (SubPc(2)) - have been employed in organic photo ...

WORLD SCIENTIFIC PUBL CO PTE LTD2022

The developed world is built on the fact that energy is readily available and functionally infinite. The electricity from the wall, the gas at the station, and the heat in our homes are reliable and low-cost. But this comfort is so far only possible throug ...

EPFL2022

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Li-TFSI/t-BP are the most widely employed p-dopants for hole-transporting materials (HTMs) within the state-of-the-art perovskite solar cells (PSCs). The hygroscopicity and migration of these dopants, however, lead to devices with limited stability. To sol ...

CELL PRESS2022

An Acetylene-Linked 9,9 '-Bicarbazole-Based Hole-Transporting Material for Efficient Perovskite Solar Cells

Jianxing Xia

A new hole-transporting material (XJ-05) based on a 9,9'-bicarbazole core and four acetylene-linked triphenylamine groups was designed and applied for perovskite solar cells (PSCs). Optical spectra, thermal stability, electrochemical properties, density fu ...

AMER CHEMICAL SOC2022

The under-coordinated defects within perovskite and its relevant interfaces always attract and trap the free carriers via the electrostatic force, significantly limiting the charge extraction efficiency and the intrinsic stability of perovskite solar cells ...

WILEY-V C H VERLAG GMBH2022

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Finding new hole-transporting materials (HTMs) suitable for replacing the state-of-the-art spiro-OMe-TAD is still challenging. In this work, newly synthesized diarylamine-substituted metal phthalocyanines (MPcs, M 1/4 Zn(II) or Cu(II)) functionalized with ...

ELSEVIER SCI LTD2022

Cyclopentadiene-Based Hole-Transport Material for Cost-Reduced Stabilized Perovskite Solar Cells with Power Conversion Efficiencies Over 23%

Michael Graetzel, Shaik Mohammed Zakeeruddin, Felix Thomas Eickemeyer, Yuhang Liu, Thomas Paul Baumeler, Hongwei Zhu, Michael Bauer

Hole transport materials (HTM) are an important component in perovskite solar cells (PSC). Despite a multitude of HTMs developed in recent years, only few of them lead to solar cells with efficiencies over 20%. Therefore, it is still a challenge to develop ...

WILEY-V C H VERLAG GMBH2021

Palliating the efficiency loss due to shunting in perovskite/silicon tandem solar cells through modifying the resistive properties of the recombination junction

Christophe Ballif, Gabriel Christmann, Mathieu Gérard Boccard, Sylvain Nicolay

As the efficiency of commercial crystalline silicon solar cells approaches its maximum theoretical value, tandem architectures are becoming increasingly popular to continue the push to higher photovoltaic performances. Thin-film materials are particularly ...

2021