Iron phosphate mediated magnetite synthesis: a bioinspired approach
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Reactions of X2 (X = Br, I), P4 and Ag(CH2Cl2)[Al(OR)4] [R = C(CF3)3] in suitable ratios to prep. naked polyphosphorus cations were carried out and led to products which suggested these elusive cations as intermediates. At temps. >-30 Deg to rt the initial ...
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