Aqueous-phase reactive species formed by fine particulate matter from remote forests and polluted urban air
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OBJECTIVE To assess risks and costs of hospital admission associated with short term exposure to fine particulate matter with diameter less than 2.5 mu m (PM2.5) for 214 mutually exclusive disease groups. DESIGN Time stratified, case crossover analyses wit ...
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Comprehensive techniques to describe the organic composition of atmospheric aerosol are needed to elucidate pollution sources, gain insights into atmospheric chemistry, and evaluate changes in air quality. Fourier transform infrared absorption (FT-IR) spec ...
Comprehensive techniques to describe the organic composition of atmospheric aerosol are needed to elucidate pollution sources, gain insights into atmospheric chemistry, and evaluate changes in air quality. Fourier transform infrared absorption (FT-IR) spec ...
The oxidative potential (OP) of fine and coarse fractions of ambient aerosols was studied in the urban environment of Athens, Greece. OP was quantified using a dithiothreitol (DTT) assay, applied to the water soluble fraction of aerosol that was extracted ...
2019
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Nitrate is one of the most abundant inorganic water-soluble ions in fine particulate matter (PM2.5). However, the formation mechanism of nitrate in the ambient atmosphere, especially the impacts of its semivolatility and the various existing forms of nitro ...
Polarizable radical sites in distonic radical anions are stabilized by ostensibly remote negative charges. Computational evidence suggests bond dissociation energies of closed-shell precursors are significantly lowered by through-space interactions with a ...
Trifluoromethylative difunctionalization and hydrofunctionalization of unactivated alkenes have been developed into powerful synthetic methodologies. On the other hand, methylative difunctionalization of olefins remains an unexplored research field. We rep ...