The not so identical twins: (dis)similarities between reactive electrophile and oxidant sensing and signaling
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Monitoring, control and optimization of chemical reaction systems often requires in-depth analysis of the underlying reaction mechanisms. This dissertation investigates appropriate tools that facilitate the analysis of homogeneous and gas-liquid reaction s ...
This dissertation is concerned with the development of a methodology and appropriate tools for the investigation of chemical reaction systems using measured data. More specifically, the determination of reaction stoichiometry and kinetics from concentratio ...
The bifunctional catalyst 6'-deoxy-6'-acylamino-beta -isocupreidine served both as a base to trigger the in situ generation of N-sulfonylimine from readily available alpha -amidosulfones and as a chiral nucleophile to initiate the enantioselective aza-Mori ...
Chem. mechanisms are used in 3D air quality models as well as for modeling lab. expts. Depending on the application the required detailedness of the mechanism differs. The mechanism generation program CHEMATA (Chem. Mechanism Adaptation to Tropospheric App ...
N,N-Dimethylsulfamide (DMS), a newly identified, ubiquitous degradation product of the fungicide tolylfluanide, has been shown to be a N-nitrosodimethylamine (NDMA) precursor during zonation. In this study, batch ozonation experiments in ultrapure buffered ...
Accelerated bleaching, photobleaching and mineralization of the non-biodegradable azo-dye, Orange II, was obsd. with oxone in solns. with Co2+-ions. The bleaching rate of Orange II in the dark was found to follow a first-order kinetics with respect to [Co2 ...
A method to obtain quantitative information about the chemical composition spatial distribution on rough (Ra between half a micrometer and tens of micrometers) surfaces is developed by using a Raman microscopy technique. It is tested on a wrinkled polyeste ...
The rapid and complete characterization of chemical reaction mechanisms is of the utmost importance in terms of chemical understanding, safety and efficiency. In this presentation a new small volume reaction calorimeter (25-45mL) is described. With this re ...
During the last few decades, air pollution has become one of the major environmental and public health issue in every important cities over the world. Photochemical pollutants, like ozone which play a central role in today's air pollution problems, are for ...
We present an investigation into femtosecond time-resolved vibrational sum frequency spectroscopy as a tool for studying ultrafast surface dynamics. It is demonstrated that the presence of experimentally observed new spectral features does not necessarily ...