Enhancing Algae Biomass Production by Using Dye-Sensitized Solar Cells as Filters

One of the most promising options for decreasing the costs of microalgae production is enhancing the production and reducing the energy demand of the culturing systems and the high surface area requirements. Because microalgae growth requires only specific wavelengths of the solar spectrum, the remaining part of the solar spectrum may be simultaneously used by a translucent photovoltaic (PV) layer to produce electricity, which leads to a reduction of space and energy requirements. This work presents the results of a new concept of a positive energy culturing system for microalgae, where the light source is selectively shared between the needs of the algal biomass through photosynthesis and the production of PV energy through dye-sensitized solar cells (DSCs). To ascertain the DSC (DSC-Red, DSC-Green) light-filtering effects on microalgal biomass, (1) the variation of growth kinetics, (2) microalgae pigments [chlorophylls-(a + b) and carotenoids], and (3) macromolecule content (carbohydrates, proteins, and lipids) were investigated and compared to control cultures under two different solar-simulated light intensities (200 and 600 W/m2). The results showed a net improvement of the growth rate and dry weight at the higher irradiance using both colored DSC filters compared to control cultures. The highest growth rates (μ) and doubling time (td) of Chlorella vulgaris cells were obtained using the DSC-Red (DSC-R) and DSC-Green (DSC-G) solar cells as filters with μ = 0.86 ± 0.01 day–1; td = 0.80 day and μ = 0.85 ± 0.03 day–1; td = 0.81 day, respectively, compared to normal glass control μ = 0.51 ± 0.03 day–1; td = 1.35 day. A significant increase in the chlorophyll-a content was obtained under low light intensity for both DSC-colored compared to control culture, and there was no significant variation in the macromolecule content measured under the tested light intensities. Finally, a life cycle assessment based on a functional unit of 1 kg of the produced algal biomass using the DSC–photobioreactor (DSC–PBR) was performed and compared to a normal glass PBR. The results were expressed in terms of CO2 emission equivalents produced and electricity generated. A fraction of electricity generated by DSC–PBR is used for bubbling, and the extra electricity is injected into the electricity grid. This resulted in net negative GHG emissions.

Experimental Determination of Optical and Thermal Properties of Semi-transparent Photovoltaic Modules Based on Dye-sensitized Solar Cells

Olivia Valérie Charlotte Bouvard, Josef Andreas Schuler, Sara Vanzo

The demand for energy efficiency of buildings and on-site electricity production is rising. Building integrated photovoltaic can provide a part of the electricity demand. Many studies are related to the module efficiency. However, architectural integration, optical and thermal properties also require attention. Semi-transparent modules are especially interesting for architectural integration in the glazed part of the façade. Dye sensitized solar cells, offering color and semi-transparency, are in the process of market introduction. However, dye-sensitized solar cells are fragile and there are not many examples of architectural integration due to the technical challenge of introducing these cells in a glazing. A glazing containing colored photovoltaic modules could be used to design an active façade. In order to determine the thermal behaviour of the building, the precise optical and thermal properties of the used materials need to be known. Performances of semi-transparent photovoltaic modules based on dye-sensitized solar cells were investigated. These modules come from the same manufacturer, using the same technology. However, they differ in terms of shades and nuances. Common practice is to indicate optical properties at normal angle of incidence. Yet, for most latitudes, the properties for a large range of angles of incidence are more relevant. Therefore, the spectral transmittance and the reflectance were measured at 12 angles of incidence ranging from 0° to 75°. From these data, the solar direct transmittance τe, the solar direct reflectance ρe and the visible transmittance τv and selectivity were calculated. The solar gain factor was determined on a prototype double glazing under illumination with a solar simulator by measuring the temperatures of the external and inner surface of the product. Combined with the values of absorptance obtained from the transmittance and reflectance values, this measurement allows us to determine the internal heat transfer coefficient qi and thus the solar gain factor of the double glazing (also called total energetic transmittance or g-value). Final performance of a façade containing these modules will depend on the composition of the double glazing in which they will be laminated. The performance of the module itself will help to determine the best composition for each climate. For instance, a solar protection coating may be needed. The modules can be laminated to a glass pane and then be assembled in a double glazing. Therefore the architectural integration is facilitated and compatible with existing façade systems. In highly glazed building, a part of the façade could then be a photovoltaic façade and deliver a fraction of the energy demand while providing colourful options to enhance the aesthetic of the building.

2015

Extraction of carotenoids from Chlorella vulgaris using green solvents and syngas production from residual biomass

Christof Holliger, Christian Ludwig, Dominik Refardt, Jean-Paul Schwitzguebel, Shivom Sharma

A combined process for carotenoids extraction and efficient bioenergy recovery from the wet microalgae biomass is proposed. High added-value products could thus be extracted prior a hydrothermal gasification of the algal biomass into synthetic natural gas. The economic sustainability of biofuel production from algal biomass as well as the large energy demands of microalgae cultivation and harvesting is addressed in this paper. Two green solvents, ethanol and 2-methyltetrahydrofuran (MTHF), were used to achieve the maximum extractability of selected carotenoids. Pure MTHF was tested for the first time as an alternative renewable solvent for carotenoid extraction from wet biomass and promising results were obtained (30 min at 110 degrees C), with 45% of total carotenoids being extracted. The energy content of the residual biomass corresponds to a High Heating Value (HHV) of 18.1 MJ/kg. With a 1: 1 mixture of both MTHF and ethanol, more carotenoids were extracted from wet biomass (66%) and the remaining HHV of the residual biomass was 15.7 MJ/kg. The perspectives of combined carotenoid extraction and energy recovery for a better microalgae valorization are discussed.

2017

Active façades : life cycle environmental impacts and savings of photovoltaic power plants integrated into the building envelope

Gianluca Cattaneo, Angela Clua Longas

Aim and approach used Increased energy supply from photovoltaics is a main priority in the “Energy Strategy 2050”. Within the joint research project "Next generation photovoltaics" funded by the Swiss National Science Foundation, we analysed different options for the enhanced integration of photovoltaic technologies into the envelope of Swiss buildings (BIPV). The PV modules for building integration are using novel monolithic silicon heterojunction organometallic perovskite tandem cells (SHJ-PSC) with adaptions to improve the visual acceptance. In a joint effort of product developers, architects and scientists, this project aimed at providing pathways for the wide-scale use of BIPV façade solutions, and developing integrated designs based on emerging high-efficiency module technologies to improve the visual aspect and acceptance of PV systems installed in Switzerland. These so-called active façades incorporating BIPV modules to generate electricity can provide a significant contribution to the energy transition away from fossil and nuclear fuels. We compared the environmental impacts of different façade construction systems with and without SHJ-PSC BIPV modules with improved visual design, using a prospective life cycle assessment with a time horizon of 2025. The comparison includes a conventional brick and roughcast façade, a timber frame façade, and the Advanced Active Façade (AAF), which integrates SHJ-PSC BIPV modules in a low embodied impact façade substructure. In addition, we compared the environmental impacts caused by the construction of the above described façades with the environmental impacts saved due to the electricity produced by BIPV modules incorporated into the AAF. 2. Scientific innovation and relevance Our research focuses on the combined expertise of life cycle thinking, PV module development and façade design. The major scientific innovations are: 1) the prospective life cycle assessment of novel monolithic silicon heterojunction organometallic perovskite tandem cells (SHJ-PSC); 2) the comparison of different façade construction systems and their environmental impacts; 3) the quantification of the saved environmental impacts arising from the electricity generated by the active façade; and 4) the visual adjustments of PV modules to improve their acceptance. The main advantage of integrating PV into building façades is the large available area, which can be limited on rooftops. In order to reach the market penetration for PV required for the energy transition, PV modules must be integrated into façades as well as into rooftops. 3. Results and conclusions An equilibrium must be achieved among different technical and aesthetic issues when integrating energy generation systems into the building envelope, especially into the façade for its public condition and exposure. Based on these prerequisites, the research team has developed the AAF which combines passive and active energy design strategies while meeting contemporary architectural requirements. This façade design is based on low-embodied-energy construction principles, it is defined by a non-loadbearing wood-panel substructure and it integrates a double layer of natural insulation: cellulose and wood-fibre. In addition, its design incorporates an opaque SHJ-PSC BIPV façade-cladding following contemporary façade design trends. (Figure 1). The use of photovoltaic modules integrated into the façade cladding or roof will increase the environmental impact of the building envelope, compared to using conventional construction materials. The environmental impacts of the AAF using PV modules are two to four times higher compared to a conventional façade. The PV modules cause the highest share of greenhouse gas emissions of the AAF with about 375 kg CO2-eq per square meter (see Figure 2). The additional materials required to build the AAF including exterior panels, insulation and other materials cause about 75 kg CO2-eq per square meter of façade. The brick and timber frame façades cause greenhouse gas emissions around 200 and 100 kg CO2-eq, respectively. If the greenhouse gas emissions caused by the PV module is excluded this will result in a reduction between 25 and 125 kg CO2-eq per square meter of façade. However, the environmental impacts of the AAF are significantly reduced if the whole life cycle is considered due to the PV electricity produced by the building. Therefore, we calculated the saved greenhouse gas emissions due to the electricity produced by the advanced active façade and fed to the European electricity grid using the greenhouse gas emissions caused by the current European electricity mix as reference. These calculated savings due to the electricity produced by the BIPV are about 4 times higher than the impacts of the advanced active façade. Incorporating BIPV panels into building’s façades will cause net savings of about 1700 kg CO2-eq per square meter over the whole life cycle of BIPV façades, while simultaneously saving up to 125 kg CO2-eq per square meter of façade for the reduced material demand to build the façade (see Figure 3). We performed this analysis for 16 different environmental impacts according to the recommended midpoints by the Joint Research Council of the European Commission. The results were comparable to greenhouse gas emissions with the net saved environmental impacts being many times higher for all the environmental impacts analysed except mineral resource use caused by the indium used in the novel SHJ-PSC tandem module (see Figure 4). To conclude, the use of PV modules in AAF can reduce the greenhouse gas emissions per square meter of façade between 25 and 60 % if the production of the PV module and its produced electricity are excluded. If the production and life cycle of the PV modules are included into the analysis the AAF will cause net greenhouse gas savings up to four times higher than the production of the AAF itself. The results for environmental impacts other than greenhouse gases were similar except for mineral resource depletion. Overall, the building integration of photovoltaic modules as AAF will reduce the environmental impacts of the building while simultaneously providing a visually appealing building envelope.

2019