Tailoring the redox-active transition metal content to enhance cycling stability in cation-disordered rock-salt oxides
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This thesis comprises the study of two types of 2D materials, those stabilized by non-covalent and those by covalent interactions. They are synthesized and studied on well-defined metallic surfaces in ultra-high vacuum (UHV). The self-assembly of terephtha ...
Recently published discoveries of acoustic- and optical-mode inversion in the phonon spectrum of certain metals became the first realistic example of noninteracting topological bosonic excitations in existing materials. However, the observable physical and ...
Soluble transition metals in particulate matter (PM) can generate reactive oxygen species in vivo by redox cycling, leading to oxidative stress and adverse health effects. Most metals, such as those from roadway traffic, are emitted in an insoluble form, b ...
In the present work, we study the effects that aggregation of humic acids in seawater, and its adsorption to surfaces, can have on the determination of Cu and Pb accumulation by phytoplankton within the context of metal bioavailability studies, using the d ...
The total resources form copper, zinc and lead was estimated from a reworking of the literature. The data was used as input to the integrated systems dynamics model BRONZE, and used to estimate the global supply of these metals and the by-products antimony ...
Electrochemical reduction of carbon dioxide, using the electricity generated from renewable energy sources, has the potential of rendering a carbon-neutral energy economy. Developing selective, efficient and robust electrocatalysts is the key step towards ...
Providing energy for a population projected to reach 9 billion people within the middle of this century is one of the most pressing societal issues. Burning fossil fuels at a rate and scale that satisfy our near-term demand will irreversibly damage the liv ...
Magnetic skyrmions are vortex-like topological spin textures often observed to form a triangular-lattice skyrmion crystal in structurally chiral magnets with the Dzyaloshinskii-Moriya interaction. Recently, beta-Mn structure-type Co-Zn-Mn alloys were ident ...
High-valent iron-oxo intermediates are implicated in a variety of oxidative enzymes, many of which are capable of the selective partial oxidn. of strong aliph. and arom. C-H bonds. However, mol. iron-oxo species often lack stability, decaying via pathways ...
The 137Cs and 210Pb dating of a 61-cm long sediment core retrieved from a drinking water reservoir (Lake Bret) located in Switzerland revealed a linear and relatively high sedimentation rate (∼1 cm/year) over the last decades. The continuous centimeter sca ...