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Investigation in Crystal Growth/Morphology and Interface Engineering of Perovskite Solar Cells by Different Deposition Methods

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Facet Engineering for Stable, Efficient Perovskite Solar Cells

Facet engineering is an important strategy for tuning the physical, chemical, and electronic properties of a crystal surface, and it also provides an effective route to improve the device performance in many fields. Complex crystal structures with rough mo ...

AMER CHEMICAL SOC2022

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Tin-lead (Sn-Pb) mixed perovskite has received widespread attention due to its suitable band gap width and high optical absorption coefficients. However, the power conversion efficiency (PCE) of Sn-Pb mixed perovskite solar cells (PSCs) is still low due to ...

ROYAL SOC CHEMISTRY2022

Hybrid halide perovskites are currently one of the most studied semiconductors. However, due to poor intrinsic and extrinsic stability, further developments to commercialize devices based on hybrid halide perovskites are limited. Many different strategies ...

EPFL2022

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Layered hybrid organic−inorganic perovskite (LHOIP) materials constructed with low-band-gap chromophore-based organic spacer cations are anemerging class of materials that promise unique tunability of their optoelectronic properties. However, the large siz ...

2022

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Vapor-based processes are promising options to deposit metal halide perovskite solar cells in an industrial environment due to their ability to deposit uniform layers over large areas in a controlled environment without resorting to the use of (possibly to ...

2021

Orientation‐Engineered Small‐Molecule Semiconductors as Dopant‐Free Hole Transporting Materials for Efficient and Stable Perovskite Solar Cells

Hong Zhang, Zhiwen Zhou, Miao Chen

Crystallized p-type small-molecule semiconductors have great potential as efficient and stable hole transporting materials (HTMs) for perovskite solar cells (PSCs) due to their relatively high hole mobility, good stability and tunable HOMOs depending on th ...

2021

Ammonia-assisted vapour transport deposition of formamidinium salts for perovskite thin films

Christophe Ballif, Quentin Thomas Jeangros, Florent Sahli, Léo Duchêne, Quentin Jean-Marie Armand Guesnay, Niccolo Salsi

Formamidinium (FA) cations commonly used in perovskite semiconductors tend to form sym-triazine when sublimed in vacuum, a process that hampers the deposition process. Here we find that ammonia, when used as a carrier gas for formamidinium halides transpor ...

2021

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Hybrid lead halide perovskites typically form polycrystalline films that have multiple grain sizes and surface defects. A key engineering challenge toward commercialization is therefore the production of homogeneous, defect-free largearea devices achieving ...

2021

Metal-halide perovskite semiconductors have attracted intense interest over the past decade, particularly for applications in photovoltaics. Low-energy optical phonons combined with significant crystal anharmonicity play an important role in charge-carrier ...

IOP PUBLISHING LTD2021

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A comprehensive picture explaining the effect of the crystal size in metal halide perovskite films on their opto-electronic characteristics is currently lacking. We report that perovskite nanocrystallites exhibit a wider band gap due to concurrent quantum ...

WILEY-V C H VERLAG GMBH2021