Publication

Carbon K-edge x-ray emission spectroscopy of gas phase ethylenic molecules

Publications associées (34)

Non-negative matrix factorization-aided phase unmixing and trace element quantification of STEM-EDXS data

Cécile Hébert, Duncan Thomas Lindsay Alexander, James Badro, Farhang Nabiei, Hui Chen

Energy-dispersive X-ray spectroscopy (EDXS) mapping with a scanning transmission electron microscope (STEM) is commonly used for chemical characterization of materials. However, STEM-EDXS quantification becomes challenging when the phases constituting the ...

Elsevier2024

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Carbon K-edge resonant Auger spectra of gas-phase allene following excitation of the pre-edge 1s -> pi* transitions are presented and analysed with the support of EOM-CCSD/cc-pVTZ calculations. X-Ray absorption (XAS), X-ray photoelectron (XPS), valence ban ...

ROYAL SOC CHEMISTRY2023

Bridging Native and Intrinsic Structures of Microhydrated Biomolecules by Cold Ion Spectroscopy

Andrei Zviagin

Solving native structures of such large molecules, like biomolecules, is often challenging, particularly due to the potentially infinite number of non-covalent interactions with water. In this thesis, we report the use of cold ion gas-phase action spectros ...

EPFL2023

With the advent of X-ray free-electron lasers (XFELs) time-resolved X-ray spectroscopic techniques have advanced to the femtosecond regime. These are element selective techniques which offer unique insight into the electronic and chemical environment and d ...

EPFL2020

From synchrotrons for XFELs: the soft x-ray near-edge spectrum of the ESCA molecule

Christoph Bostedt

A predictive understanding of soft x-ray near-edge absorption spectra of small molecules is an enduring theoretical challenge and of current interest for x-ray probes of molecular dynamics. We report the experimental absorption spectrum for the electron sp ...

2020

Ruthenium on phosphorous-modified alumina as an effective and stable catalyst for catalytic transfer hydrogenation of furfural

Davide Ferri, Oliver Kröcher, Gaël Peng

Supported ruthenium was used in the liquid phase catalytic transfer hydrogenation of furfural. To improve the stability of Ru against leaching, phosphorous was introduced on a Ru/Al2O3 based catalyst upon impregnation with ammonium hypophosphite followed b ...

2020

Attosecond transient absorption spooktroscopy: a ghost imaging approach to ultrafast absorption spectroscopy

Christoph Bostedt, Zhaoheng Guo, Jonas Knurr, Andre Al Haddad, Siqi Li

The recent demonstration of isolated attosecond pulses from an X-ray free-electron laser (XFEL) opens the possibility for probing ultrafast electron dynamics at X-ray wavelengths. An established experimental method for probing ultrafast dynamics is X-ray t ...

ROYAL SOC CHEMISTRY2020

One-dimensional facile growth of MAPbI(3) perovskite micro-rods

Mohammad Khaja Nazeeruddin, Zubair Ahmad

One-dimensional microrods (4-5 mm) of PbI2 and CH3NH3PbI3 (MAPbI(3)) with unique structural and morphological properties have been grown at room temperature. X-ray diffraction (XRD) patterns of both types of micro-rods exhibit a hexagonal system (P3m1(164) ...

ROYAL SOC CHEMISTRY2019

The effect of beryllium oxide on retention in JET ITER-like wall tiles

Olivier Sauter, Ambrogio Fasoli, Basil Duval, Stefano Coda, Jonathan Graves, Yves Martin, Duccio Testa, Patrick Blanchard, Alessandro Pau, Cristian Sommariva, Henri Weisen, Richard Pitts, Yann Camenen, Jan Horacek, Javier García Hernández, Marco Wischmeier, Nicola Vianello, Mikhail Maslov, Federico Nespoli, Yao Zhou, David Pfefferlé, Davide Galassi, Antonio José Pereira de Figueiredo, Jonathan Marc Philippe Faustin, Liang Yao, Dalziel Joseph Wilson, Hamish William Patten, Samuel Lanthaler, Bernhard Sieglin, Otto Asunta

Preliminary results investigating the microstructure, bonding and effect of beryllium oxide formation on retention in the JET ITER-like wall beryllium tiles, are presented. The tiles have been investigated by several techniques: Scanning Electron Microscop ...

ELSEVIER2019

Determining alloy composition in MoxW(1-x)S2 from low wavenumber Raman spectroscopy

Mixed alloy MoxW(1-x)S2 (0x1) bulk samples are characterized by low wavenumber Raman spectroscopy. The results provide a convenient and reliable means for systematically determining the sample Mo/W composition. The absence of disorder effects in its interl ...

Wiley2017

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