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New ternary and higher order inorganic materials are needed for a large variety of applications, yet their synthesis still represents a chemistry challenge. Herein, we focus on the synthesis of Cu-M-S nanocrystals (where M = V, Cr, Mn) via a wet-chemistry ...
Nature carefully selects specific metal ions for incorporation into the enzymes that catalyse the chemical reactions necessary for life. Hydrogenases, enzymes that activate molecular H-2, exclusively utilize Ni and Fe in [NiFe]-, [FeFe]- and [Fe]-hydrogean ...
Water splitting offers the opportunity for storing solar energy and, thus, producing carbon-neutral and renewable solar fuels. The process, known as artificial photosynthesis, is limited by the electrocatalytic conversion of water into molecular oxygen. El ...
Nowadays, mankind is facing an important energy challenge. Depletion in fossil fuels reserves and increasing energy demand, coupled with the problematic greenhouse effect induced by massive anthropogenic release of carbon dioxide into the atmosphere, are d ...
This thesis reports on the growth and on the magnetic characterization of nanostructures made of 3d-4d transition metals and rare earths. In all the experiments the nanostructures have been grown by atomic beam epitaxy (ABE) in ultra high vacuum conditions ...
The search for highly active earth-abundant elements and nonexpensive catalysts for hydrogen evolution reaction is a vital and demanding task to minimize energy consumption. Transition metals incorporated into molybdenum sulfides are promising candidates f ...
In this thesis, Ni catalysts derived from perovskite-type metal oxides (PMO, general formula ABO3, A=lanthanide or earth alkaline element, B=transition metal) are investigated as a potential class of materials, which are able to overcome thechallenges of c ...
Siberian scientists showed by their scientific investigations that brines of Siberian Platform are a very important hydro mineral resource for economical development of the East Russia. Prospects for the integrated mining of the hydromineral resources in R ...
High levels of ammonia (NH3) have been suggested to elevate ambient particle pH levels to near neutral acidity (pH = 7), a condition that promotes rapid SO2 oxidation by NO2 to form aerosol sulfate concentration consistent with "London fog" levels. This po ...
Water splitting is the essential chemical reaction to enable the storage of intermittent energies such as solar and wind in the form of hydrogen fuel. The oxygen evolution reaction (OER) is often considered as the bottleneck in water splitting. Though meta ...
