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In Operando, Photovoltaic, and Microscopic Evaluation of Recombination Centers in Halide Perovskite-Based Solar Cells

Publications associées (40)

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The hole transporting material (HTM) is an essential component in perovskite solar cells (PSCs) for efficient extraction and collection of the photoinduced charges. Triphenylamine- and carbazole-based derivatives have extensively been explored as alternati ...

Amer Chemical Soc2016

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New technologies launch novel materials; besides their performances in products, their health hazards must be tested. This applies to the lead halide perovskite CH3NH3PbI3 as well, which offers fulgurate applications in photovoltaic devices. We report the ...

Royal Soc Chemistry2016

Unravel the Impact of Anchoring Groups on the Photovoltaic Performances of Diketopyrrolopyrrole Sensitizers for Dye-Sensitized Solar Cells

Michael Graetzel, Mohammad Khaja Nazeeruddin, Peng Gao, Aswani Yella, Thomas Wesley Holcombe, Paramaguru Ganesan

Two D-pi-A dyes, one with a strong electron withdrawing cyanoacrylic acid DPP 20 and one with a weak acceptor carboxylic acid DPP 21 have been synthesized and characterized for their application in dye-sensitized solar cells. This allows us to understand t ...

Amer Chemical Soc2015

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We report on the synthesis, and photovoltaic performances of four novel Ru(II)-bipyridine heteroteptic complexes TT206-209, incorporating branched and bulkier alkyl chains compared to their linear analogues C106 and CYC-B11 previously reported. In both ser ...

Royal Society of Chemistry2014

Molecular gelation of ionic liquid-sulfolane mixtures, a solid electrolyte for high performance dye-sensitized solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Jean-David Décoppet, Thomas Moehl

Cyclohexanecarboxylic acid-[4-(3-tetradecylureido)phenyl]amide is an efficient gelator to solidify ionic liquid electrolytes. In this paper we apply this low molecular weight gelator to solidify the newly prepared sulfolane based ionic liquid electrolyte. ...

Royal Society of Chemistry2014

High performance solid-state mesoscopic solar cells

Julian Burschka

Mesoscopic sensitized solar cells are one of the most promising third-generation photovoltaic technologies. Dye-sensitized solar cells (DSCs), imitating the photosynthesis of green plants, were the first photovoltaic devices to utilize a mesoscopic heteroj ...

EPFL2013

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A new cobalt-terpyridine redox shuttle (Co(Cl-phenyl-terpyridine)(2)) has been synthesized, characterized, computationally investigated and then tested in photovoltaic devices, in conjunction with the prototypical N719 and Z907 ruthenium dyes. Low ...

Elsevier2013

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A simple cell architecture that achieves enhanced light harvesting with less dye quantity while simultaneously improving the power conversion efficiency (PCE) of dye-sensitized solar cells is presented. Polystyrene (PS) spheres of sub-micrometer size were ...

Royal Society of Chemistry2012

Molecular-Scale Interface Engineering of Nanocrystalline Titania by Co-adsorbents for Solar Energy Conversion

Michael Graetzel, Shaik Mohammed Zakeeruddin, Mingkui Wang, Robin Humphry-Baker, Péter Kalman Péchy

The use of mixed self-assembled monolayers, combining hydrophobic co-adsorbents with the sensitizer, has been demonstrated to enhance the efficiency of dye-sensitized solar cells (DSCs). Herein, the influence of the anchoring groups of the co-adsorbents on ...

2012

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We report on the impact of the doping concentration design on the performance of silicon microwire arrays as photovoltaic devices. We have fabricated arrays with different p- and n-doping profiles and thicknesses, obtaining mean efficiencies as high as 9.7 ...

Wiley-VCH Verlag Berlin2012