Publication

Influence of the molecular weight and physical properties of a thermoplastic polymer on its dynamic wetting behavior

Publications associées (44)

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Soft Mechanochemistry of Disulfide-Crosslinked Polymer Networks

Zhao Meng

Mechanochemistry harnesses mechanical force to facilitate chemical reactions. Traditionally, the field of polymer mechanochemistry has used methods to activate chemical bonds, which use forces that are larger than those that are required to break a covalen ...

EPFL2024

Architecturally Diverse Polymer Brushes Prepared via Surface-Initiated Atom Transfer Radical Polymerization

Sabrina Sant

Polymer brushes, which are polymers anchored to a solid substrate by one chainend, have the ability to modify the properties of an underlying substrate, offeringintriguing features such as enhanced lubrication, reduced friction, colloidal stability, and an ...

EPFL2023

Thermoset rubbers give rise to elastomers with tunable stiffness and high resilience but are not recyclable. Thermoplastic elastomers can address this problem but their broad applicability is impeded by either limited operating temperatures or inferior ela ...

EPFL2023

Thermoplastic Toughening of a Semiaromatic Polyamide with an Amino-telechelic Polyethylene

John Christopher Plummer, Holger Frauenrath, Michael Alan Giffin

Semiaromatic polyamides are used for metal replacementin advancedengineering applications to reduce weight and improve efficiency,but their range of application is limited by their inherent lack ofductility and toughness. Here, we combined semiaromatic pol ...

AMER CHEMICAL SOC2023

Polymers with high surface electric insulation capability are greatly demanded in various electrical devices operating in vacuum ambient. Low secondary electron emission (SEE) is favorable to mitigate vacuum flashover by inhibiting the SEE avalanche across ...

ELSEVIER2022

Mechanical Activation of Chemical Bonds at Polymer Interfaces

Julian Nicolas Bleich

Polymer brushes are a specific class of polymer thin films in which each chain is tethered to the underlying substrate via one chain end. In sufficiently densely grafted assemblies, the individual polymer chains are forced into an extended chain conformati ...

EPFL2021

This Thesis is built around 4 topics, which share in common that they all take advantage of the assets of controlled radical polymerization to either (i) prepare well-defined model systems to address fundamental research questions with regard to the sensit ...

EPFL2020

Thermoplastic polyurethanes (TPUs) are designed using a large variety of basic building blocks but are only synthesized in a limited number of solvent systems. Understanding the behavior of the copolymers in a selected solvent system is of particular inter ...

AMER CHEMICAL SOC2019

Hierarchical porous structure

Dominique Pioletti, Pierre-Etienne Bourban, Matteo Gregorio Modesto Marascio

Cellular thermoplastic structures with hierarchical multi-scale porosity (preferably 1-300 µm micro-porosity to 0.3-10 mm macro-porosity) are produced from an integrated approach of 3D printing, preferably by Fused Deposition Modeling (FDM), and of supercr ...

2018

Synthesis and Characterisation of Semiaromatic Polyamides Comprising Benzofurobenzofuran Repeating Units

Rosario Scopelliti, Farzaneh Fadaei Tirani, Holger Frauenrath, Daniel Görl, Alberto Fabrizio, Bilal Özen, Thomas Schmaltz, Julien Philippe Cretenoud

Semiaromatic polyamides are attractive engineering polymers owing to their outstanding thermo-mechanical properties. To expand the scope of semiaromatic polyamides by additional optoelectronic features, one may consider the incorporation of extended pi-con ...

2017