Speciation of Lanthanide Metal Ion Dopants in Microcrystalline All-Inorganic Halide Perovskite CsPbCl3
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Europium, terbium, dysprosium, and samarium are the main trivalent lanthanide ions emitting in the visible spectrum. In this work, the potential of these ions for colorimetric applications and colour reproduction was studied. The conversion of spectral dat ...
Out of the 14 lanthanide (Ln) ions, molecular complexes of Ln(IV) were known only for cerium and more recently terbium. Here we demonstrate that the +IV oxidation state is also accessible for the large praseodymium (Pr) cation. The oxidation of the tetraki ...
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Cation ordering is expected to influence the properties of oxides in the ZrO2−YTaO4 system, but the ordering patterns and their relative energies are not well understood. This work investigates the stability of zirconium-yttrium-tantalum orderings over the ...
Lanthanides (Ln) usually occur in the +3, or more recently the +2, oxidation states. The only example of an isolated molecular Ln(4+) so far remains Ce4+. Here we show that the +4 oxidation state is also accessible in a molecular compound of terbium as dem ...
