A continuous-wave and pulsed X-band electron spin resonance spectrometer operating in ultra-high vacuum for the study of low dimensional spin ensembles
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Electron Beam Induced Deposition (EBID) allows deposition of three-dimensional micro- and nano-structures of conductive and insulating materials on a wide range of substrates. The process is based on the decomposition of molecules of a pre-selected precurs ...
We present an EPR study of two Gd(III) complexes in aqueous solution at multiple temperatures and EPR frequencies. These two complexes, [Gd(TPATCN)] and [Gd(DOTAM)(H2O)]3+, display remarkably sharp lines (i.e. slow transverse electron spin relaxation) in c ...
Catalytic processes and in particular heterogeneous catalysis are vital for todays industry. However, many industrial catalytic processes require high temperatures and pressures to work efficiently. This stands in contrast to biological catalysts, which fu ...
In this paper we present the fabrication and characterization of highly sensitive cantilevers, with and without magnetic tip, used for magnetic resonance force microscopy experiments. The full wafer silicon batch microfabrication was successful and the ach ...
Employing higher oscillation modes of microcantilevers promises higher sensitivity when applied as sensors, for example, for mass detection or in atomic force microscopy. Introducing a special cantilever geometry, we show that the relation between the reso ...
C59N magnetic fullerenes inside single-wall carbon nanotubes (SWCNTs) are used to probe the density of states (DOS) on the host tubes using electron spin resonance (ESR). The C59N radicals are separated by C60 fullerenes to prevent dimerization and C59N-C6 ...
In the search for highly efficient magnetic resonance imaging contrast agents, polyaminopolypyridinecarboxylate complexes of Gd3+ have shown unusual properties with both very rapid and very slow electron spin relaxation in solution observed by electron par ...
Many applications in materials science, life science and process control would benefit from atomic force microscopes (AFM) with higher scan speeds. To achieve this, the performance of many of the AFM components has to be increased. In this work, we focus o ...
The detection of higher modes of oscillation in atomic force microscopy can provide additional information on sample properties. However, the limited bandwidth of the photodiode in the beam deflection detection technique often limits the detectable frequen ...
In this thesis, the magnetic and structural properties of layered epitaxial film systems and clusters are presented. A main achievement is the investigation of the direct correlation between magnetism and structural or morphological details of ultrathin fi ...