Reaction and flow variants/invariants for the analysis of chemical reaction data
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The possibility to increase the performance (productivity or selectivity) of a chemical reactor by using periodic variations of reaction parameters (e.g. reactant concentration or temperature) has been theoretically envisaged since the beginning of the 70t ...
Accelerated bleaching, photobleaching and mineralization of the non-biodegradable azo-dye, Orange II, was obsd. with oxone in solns. with Co2+-ions. The bleaching rate of Orange II in the dark was found to follow a first-order kinetics with respect to [Co2 ...
Following several tragic chemical accidents that have occurred in recent years, some directives concerning chemical process safety have been issued. The Seveso directive, for example, requires a precise description of the consequences of a possible chemica ...
Batch experiments were conducted to determine whether sub-ppb concentrations of dissolved Cr(VI) could be achieved by redox-assisted coagulation with Fe(II). in this process Fe(II) acts as a reductant for Cr(VI) and, after its oxidation to Fe(Ill), as a co ...
The authors address feature-size dependence in Ar/Cl2 chemically assisted ion beam etching (CAIBE) in the context of the fabrication of photonic crystal (PhC) structures. They systematically investigate the influence of various parameters such a ...
In this publication, several stainless steel microstructure reactors specially designed to obtain rapid and periodic temperature changes are presented. Different microstructure reactor designs have been manufactured and tested for their thermal behaviour a ...
The goal of our project (HES-SO n°11246) is to develop chemometric methods that enhance the development of chemical reactions. Semi-batch experiments are performed using a fully automated chemical reactor. Real-time analytical data, infrared (IR) spectra f ...
This project aims at the optimization of chemical reactions by using online analytical and chemometric methods. The experiments are carried out in a fully automated chemical reactor (1 liter). The host computer controls the standard process variables such ...
We derive a nonlinear stabilized Galerkin approximation of the Laplace operator for which we prove a discrete maximum principle on arbitrary meshes and for arbitrary space dimension without resorting to the well-known acute condition or generalizations the ...
The rapid and complete characterization of chemical reaction mechanisms is of the utmost importance in terms of chemical understanding, safety and efficiency. In this presentation a new small volume reaction calorimeter (25-45mL) is described. With this re ...