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Dimensionally Stable Anodes (DSA®) are electrodes composed of a metal support and an oxide coating (catalyst). Particularly in this thesis, the Ti/IrO2 electrode was used for the study of the fraction of the surface which participates effectively in the in ...
The subject of this work is the study of the electrochemical promotion of catalysis (EPOC), also called non-Faradaic electrochemical modification of catalytic activity (NEMCA). In this phenomenon, application of small currents or potentials on catalysts in ...
A novel polyol synthesis was adopted to synthesize nano-structured LiMnPO4. This route yields well-crystallized nanoparticles with platelet morphology that are only similar to 30 nm thick oriented in the b direction. The obtained material presented a good ...
The electrochemical oxidation of 3,4-(methylenedioxy)phenylmethanol (piperonyl alcohol) was characterized by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). Two electrochemical oxidation signals were found for piperonyl alcohol. T ...
The carbon-free LiFePO4 (olivine) was modified by a monolayer coverage with [12-(2,5-di-tert-butyl-4-methoxy-phenoxy)-dodecyl]-phosphonic acid, coded DW. Thin film electrodes were bonded with 5% PVDF and deposited on F-doped SnO2 (FTO) support. The surface ...
The electrochemical degradation of saturated solutions of herbicides 4-chloro-2-methylphenoxyacetic acid, 2-(4-chlorophenoxy)-2-methylpropionic acid and 2-(4-chloro-2-methylphenoxy)propionic acid in 1 M HClO4 on a boron-doped diamond (BDD) thin film anode ...
LiMnPO4 was synthesized using a sol–gel method and tested as a cathode material for lithium ion batteries. After calcination at temperatures between 520 and 600 ◦C, primary particle sizes in the range of 140–220 nm were achieved. Subsequent dry ball millin ...
The conventional strategy of overcharge protection for lithium ion batteries uses redox molecules having oxidation potential higher than the cathodic materials in the electrolyte. Here we propose a novel approach by using redox molecules having reduction p ...
Ultracapacitors, also called electrochemical double layer capacitors (EDLC) or supercapacitors, may improve the performance of conventional electrolytic capacitors in terms of specific energy, or improve the performance of rechargeable batteries in terms o ...
Alternative cathode materials were investigated for application to high voltage lithium ion batteries. Manganese based materials were considered due to the low cost and environmentally sustainable impact. Layer-structured oxide and phospho-olivine material ...