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The title compd. was obtained by reaction of (tert-BuO)3SiSH with metallic Li. Crystals are monoclinic, space group P21/n, with a 13.088(3), b 27.188(5), c 17.525(4) .ANG., b 102.25(3) Deg; Z = 2, dc = 1.083; R = 0.036, Rw(F2) = 0.105 for 11,732 reflection ...
Among the numerous base metals tested for DSA type electrodes (e.g., titanium and its alloys, zirconium, niobium etc.), tantalum is a potentially excellent substrate owing to its good elec. cond. and corrosion resistance, and the favorable dielec. properti ...
Ozone prodn. in 5M H2SO4 with Ti/IrO2/SnO2 - Sb2O5 electrodes was studied. Electrodes were prepd. at 550 Deg by spray pyrolysis of a soln. of precursors contg. tin and antimony chlorides. The aim of this work was to elucidate the mechanism of activation an ...
Electrochem. insertion of lithium in nanoporous and CVD samples of anatase was studied by chronoamperometry. The currents following cathodic and anodic potential steps were monitored as a function of film thickness, temp., and electrolyte concn. The time d ...
For the development of an elec. rechargeable zinc/air battery, La0.6Ca0.4CoO3-catalyzed (perovskite) bifunctional oxygen electrodes and pasted zinc electrodes were prepd. and tested in a monopolar zinc/oxygen cell. In addn., a bipolar Zn/oxygen stack was t ...
Electrochem. oxidn. of orgs. at thermally prepd. dimensionally stable metal oxide anodes (DSA) has been studied. In reactions involving only simple electron transfer, oxide electrodes exhibit an electrocatalytic activity similar to that of noble metal elec ...
For the development of a rechargeable zinc/air battery, La0.6Ca0.4CoO3 (perovskite) catalyzed bifunctional oxygen electrodes and 3-D zinc electrodes were prepd. and tested in a bipolar zinc/air battery. In addn., a numerical model for the zinc electrode wa ...
For the development of a rechargeable zinc/air battery, La0.6Ca0.4CoO3-catalyzed (perovskite) bifunctional oxygen electrodes and pasted zinc electrodes were prepd. and tested in monopolar zinc/air cells. In addn., a bipolar Zn/air stack was tested using re ...
The electrochem. oxidn. of PhOH in wastewater was studied using Pt and DSA anodes. Anal. of reaction intermediates and measurements of current efficiency have shown that traditional anode materials (Pt, Ti/IrO2, Ti/RuO2, Ti/PbO2) give relatively low curren ...
In a high capacity primary or secondary cell, the active material of at least one of the electrodes is selected from transition metal oxides or their (partially) lithiated forms, such as TiO2, Nb2O5, HfO2, MnO2, LiyNiO2, LiyCo2, Ldy(NiCo)O2, or LiyMn2O4, i ...
