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Influence of pH on the chloride binding capacity of Limestone Calcined Clay Cements (LC3)

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Investigation of C-A-S-H composition, morphology and density in Limestone Calcined Clay Cement (LC3)

Karen Scrivener, Emmanuelle Boehm Courjault, François Henri Avet

In this study, the C-A-S-H composition, morphology and density are characterized for Limestone Calcined Clay Cement (LC3-50) blends containing clays with various kaolinite contents. Significant incorporation of aluminium is observed for LC3-50 blends compa ...

Pergamon-Elsevier Science Ltd2019

Stability profiles of transition metal oxides in the oxygen evolution reaction in alkaline medium

Xile Hu, Aliki Moysiadou

The electrochemical water splitting reaction can convert renewable electricity into clean hydrogen fuel. The efficiency of water splitting is limited to a large extent by the sluggish oxygen evolution reaction (OER). Numerous transition metal oxides have b ...

Royal Society of Chemistry2019

Effect of Ions and Admixtures on the Growth of Synthetic Calcium Silicate Hydrate (C-S-H)

Jirawan Siramanont

This thesis investigates the effect of different parameters such as Fe (III), D-gluconate and heterogeneous particles on the nucleation and growth of synthetic C-S-H by using the dropwise precipitation method. Firstly, the effect of Fe (III) on the synthet ...

EPFL2018

Reactivity and Performance of Limestone Calcined-Clay Cement (LC3) Cured at Low Temperature

Karen Scrivener, Franco Alberto Zunino Sommariva

Limestone calcined-clay cements (LC3) take advantage of the synergetic effects of calcium carbonate reaction with the additional aluminium provided by the calcined clay. As temperature decreases, calcium carbonate solubility increase, therefore, the early- ...

SPRINGER2018

Alkali Silica Reaction and Sulfate Attack: Expansion of Limestone Calcined Clay Cement

Karen Scrivener, Aurélie Rosine Favier

In this paper, two durability issues: Alkali Silica Reaction (ASR) and external sulfate attack were studied. The results of expansion were presented for a Normal Portland cement and a blended cement LC3 containing calcined clay and limestone as supplementa ...

SPRINGER2018

Orientational ordering of water in extended hydration shells of cations is ion-specific and is correlated directly with viscosity and hydration free energy

Yixing Chen, Sylvie Roke, Halil Ibrahim Okur, Chung-Wen Liang

Specific ion effects in aqueous solutions are investigated at the molecular, nanoscopic and macroscopic levels. Femtosecond elastic second harmonic scattering (fs-ESHS) is used here to assess the chemical effects of ions on molecular and nanoscopic length ...

2017

Functional Engineering of Perovskite Nanosheets: Impact of Lead Substitution on Exfoliation in the Solid Solution RbCa2-xPbxNb3O10

Filip Mateusz Podjaski, Teresa Katharina Dennenwaldt

Tuning the chemical composition and structure for targeted functionality in two-dimensional (2D) nanosheets has become a major objective in the rapidly growing area of 2D materials. In the context of photocatalysis, both miniaturization and extending the l ...

Wiley-V C H Verlag Gmbh2017

Microengineered Electrochemical Tools for in-situ Monitoring of Marine Environment

Marianna Fighera

Measuring the concentration of different compounds in aquatic ecosystem and understanding their impact on the environment are some of the main objectives in the environmental monitoring field. Trace metals, nutrients, volatile organic compounds (VOCs), bio ...

EPFL2017

Water Exchange on [Ln(DO3A)(H2O)2] and [Ln(DTTA–Me)(H2O)2]− Studied by Variable Temperature, Pressure, and Magnetic Field NMR

Lothar Helm, Shima Karimi

Water exchange kinetics of [Ln(L)(H2O)2]x complexes (Ln = Pr, Nd, Dy, Tm, and Yb; L = DO3A and DTTA–Me) were studied by 17O NMR spectroscopy as a function of temperature, pressure, and frequency and by 1H nuclear magnetic relaxation dispersion. Water excha ...

American Chemical Society2016

Critical influence of chloride ions on silver ion-mediated acute toxicity of silver nanoparticles to zebrafish embryos

Kristin Schirmer, Renata Behra

The toxicity of silver nanoparticles (AgNP) to aquatic organisms, including zebrafish (Danio rerio), has been demonstrated, but differing opinions exist on the contribution of the physical properties of the particles themselves and the free dissolved silve ...

Informa Healthcare2015

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