Fuel Cell Modeling and Simulations

Fundamental and phenomenological models for cells, stacks, and complete systems of PEFC and SOFC are reviewed and their predictive power is assessed by comparing model simulations against experiments. Computationally efficient models suited for engineering design include the (1+1) dimensionality approach, which decouples the membrane in-plane and through-plane processes, and the volume-averaged-method (VAM) that considers only the lumped effect of pre-selected system components. The former model was shown to capture the measured lateral current density inhomogeneities in a PEFC and the latter was used for the optimization of commercial SOFC systems. State Space Modeling (SSM) was used to identify the main reaction pathways in SOFC and, in conjunction with the implementation of geometrically well- defined electrodes, has opened a new direction for the understanding of electrochemical reactions. Furthermore, SSM has advanced the understanding of the COpoisoning- induced anode impedance in PEFC. Detailed numerical models such as the Lattice Boltzmann (LB) method for transport in porous media and the full 3-D Computational Fluid Dynamics (CFD) Navier-Stokes simulations are addressed. These models contain all components of the relevant physics and they can improve the understanding of the related phenomena, a necessary condition for the development of both appropriate simplified models as well as reliable technologies. Within the LB framework, a technique for the characterization and computer- reconstruction of the porous electrode structure was developed using advanced pattern recognition algorithms. In CFD modeling, 3-D simulations were used to investigate SOFC with internal methane steam reforming and have exemplified the significance of porous and novel fractal channel distributors for the fuel and oxidant delivery, as well as for the cooling of PEFC. As importantly, the novel concept has been put forth of functionally designed, fractal-shaped fuel cells, showing promise of significant performance improvements over the conventional rectangular shaped units. Thermo-economic modeling for the optimization of PEFC is finally addressed.

Computational fluid dynamics for naval engineering problems

Nicola Parolini

The subject of this thesis is the numerical simulation of viscous free-surface flows in naval engineering applications. State-of-the-art numerical methods based on the solution of the Navier-Stokes equations are used to predict the flow around different classes of boats. We investigate the role of the Computational Fluid Dynamics in the design of racing boats, such as America's Cup yachts and Olympic class rowing hull. The mathematical models describing the different aspects of the physical problem, as well as the numerical methods adopted for their solution, are introduced and critically discussed. The different phases of the overall numerical simulation procedure, from grid generation through the solution of the flow equations to the post-processing of the results, are described. We present the numerical simulations that have been performed to investigate the role of different design parameters in the conception of America's Cup yachts and we describe how the results obtained from the simulations are integrated into the overall design process. The free-surface flow around an Olympic rowing boat is also considered. We propose a simplified approach to take into account the effect of the boat dynamics in the prediction of the hydrodynamic forces acting on the boat. Based on the results of the simulations, we propose a new design concept and we investigate its potential benefits on the boat performances. One of the aspects that is found to be not completely satisfactory, within the standard numerical methods adopted, is the modelling of complex free-surface flows. The second part of this thesis is devoted to a more theoretical and methodological investigation of this aspect. In particular, we present and analyse a new numerical method based on the level set approach for the solution of two-fluid flows. The numerical scheme based on a finite element discretization is introduced and different critical aspects of its implementation are discussed. In particular, we present and analyse a new technique for the stabilization of the advection equation associated to the level set problem. Moreover, we propose a new reinitialization procedure for the level set function which plays a crucial role in the accuracy of the algorithm. The convergence properties of this procedure are analysed and comparisons with more standard approaches are presented. Finally, the proposed method has been used to solve a variety of test cases concerning time dependent two-fluid viscous flows. The results of the simulation are presented and discussed.

EPFL2004

Numerical simulation using RANS-based tools for America's Cup design

Nicola Parolini, Mark Sawley

The application of Computational Fluid Dynamics simulations based on the Reynolds Averaged Navier- Stokes (RANS) equations to the design of sailing yachts is becoming more commonplace, particularly for the America's Cup. Drawing on the experience of the Ecole Polytechnique FÃ©dÃ©rale de Lausanne as Official Scientific Advisor to the Alinghi Challenge for the Americaâs Cup 2003, the role of RANS-based codes in the yacht design process is discussed. The strategy for simulating the hydrodynamic flow around the boat appendages is presented. Two different numerical methods for the simulation of wave generation on the water surface are compared. In addition, the aerodynamic flow around different sail configurations is investigated. The benefits to the design process as well as its limitations are discussed. Practical matters, such as manpower and computational requirements, are also considered.

2003

Numerical approximation of the Navier-Stokes-Forchheimer equations and application to a passive flow control problem

Loïc Hausammann

The modeling of an incompressible fluid through a porous medium requires to deal with two systems of partial differential equations (PDEs) for the two types of media (fluid and porous). A possible way to couple theses two equations is by using the penalization approach. The latter consists in adding to the Navier- Stokes equations modeling the fluid flow a term simulating the porous medium, so that only one PDE has to be solved. The discretization in space is done by means of the finite element method (FEM), which will be suitably stabilized in order to employ equal order approximations for both the pressure and velocity variables. Finally, a passive flow control is analyzed.

2015

Computational fluid dynamics for naval engineering problems

Nicola Parolini

EPFL2004