Reaction of triangulo-clusters [Pt-3(mu-CO)(3)(PR3)(3)] with hehafluorobutyne. The X-ray crystal structures of [Pt-2(CO)(2)(PR3)(2)(mu-eta(2):eta(2)-CF3 C CCF3)] (PR3 = PPh3 or PCy3) and [Pt-2(CO)(2) (PBzPh(2))(mu-eta(1):eta(1)-CF3C CCF3)(2)]
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The polydentate phosphinoamines 1,3-{(Ph2P)(2)N}(2)C6H4 and 2,6-{(Ph2P)(2)N}(2)C5H3N have been prepared in a single step from the reaction of the amines 1,3-(NH2)(2)C6H4 or 2,6-(NH2)(2)C5H3N with Ph2PCl in presence of Et3N (1:4:4 molar ratio) in CH2Cl2. Re ...
A complex of molecular Na2SiF6, stabilised by two 12-metallacrown-3 host complexes, has been synthesised and characterised by single crystal X-ray diffraction. ...
The reactivity of the iminodiphosphane C6H4(o-CN)N= PPh2-PPh2, which contains an N=P-P unit, has been investigated. Reaction with small molecules, [viz. H2O/O-2, H2O2, CH3OH, C6H4(o-CN)NH2] and elemental sulfur result in cleavage of the P-P bond to give am ...
LaCoO3 perovskite was prepared at 700degreesC using citrate precursors. The product was then characterized with X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS). The powder XRD pattern indicates rhomboliedral (R (3) over barc) or its monocli ...
In aqueous solutions under mild conditions, Ru(H2O)(6) was reacted with various water-soluble tertiary phosphines. As determined by multinuclear NMR spectroscopy, reactions with the sulfonated arylphosphines L = mtppms, ptppms and mtppts yielded only ...
The reaction of the anilines RNH2 [R = C6H4(o-CN), C6H4(p-CN), C6H4(m-CN), C6H4(o-C6H5), C6F5 and C6H4(o-CF3)] with Ph2PCl and inorganic or organic bases in differing stoichiometry and in different solvents has been studied. The electronic properties and s ...
The molecular forms of LiF, LiFHF and Na2SiF6 have been stabilized using trinuclear metallamacrocyclic complexes of (cymene)Ru-II, (Cp*)Rh-III and (Cp*)Ir-III as specific receptors. The host-guest complexes were characterized by NMR spectroscopy and single ...
We present a way to fabricate high-aspect-ratio silicon microcavity arrays which can be used for the investigation of confinement-induced ordering phenomena within colloid solutions. In these studies, the microcavity arrays serve as containers for confinem ...
Reactions designed to give Se6[Sb(OTeF5)6]2 by the reaction of Se2Br2, 4Se, and 2Ag[Sb(OTeF5)6] lead to products that include [Ag2(Se6)(SO2)2][Sb(OTeF5)6]2 (1). The distorted cubic (Ag2Se6+2)n consists of a Se6 mol. bicapped by two silver cations (local D3 ...
Reaction of the dimer [(η5-C5Me5)RhCl(μ2-Cl)]2 with 2 or 4 equiv of the water-soluble phosphine 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (pta) affords [Rh(η5-C5Me< ...
