Metal-Stabilized Boronate Ester Cages

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Load-bearing hydrogels ionically reinforced through competitive ligand exchanges

Esther Amstad, Matteo Hirsch, Ran Zhao, Mathias Steinacher

Fast advances in soft robotics and tissue engineering demand for new soft materials whose mechanical properties can be interchangeably and locally varied, thereby enabling, for example, the design of soft joints within an integral material. Inspired by nat ...

ROYAL SOC CHEMISTRY2021

Color-tunable emitter material

Berend Smit, Fatmah Ebrahim, Christopher Patrick Ireland

The invention is directed to a color-tunable emitter material comprising a crystal containing complexes of luminescent biomolecule-based ligands and metal ions and to a method for preparing the color-tunable emitter material. Furthermore, the invention rel ...

2021

Computer Simulation of the Surface of Aqueous Ionic and Surfactant Solutions

Mária Lbadaoui-Darvas

The surface of aqueous solutions of simple salts was not the main focus of scientific attention for a long while. Considerable interest in studying such systems has only emerged in the past two decades, following the pioneering finding that large halide io ...

AMER CHEMICAL SOC2022

The influence of chemical composition, aerosol acidity, and metal dissolution on the oxidative potential of fine particulate matter and redox potential of the lung lining fluid

Athanasios Nenes, Andrea Mario Arangio

Air pollution is a major environmental health risk and it contributes to respiratory and cardiovascular diseases and excess mortality worldwide. The adverse health effects have been associated with the inhalation of fine particulate matter (PM2.5) and indu ...

PERGAMON-ELSEVIER SCIENCE LTD2021

Development of a novel carboxamide-based off-on switch fluorescence sensor: Hg2+, Zn(2+)and Cd2+

Kurt Schenk

Here, the carboxamide ligandN-(thiazole-2-yl) picolinamide (L) was synthesized in an ionic liquid tetrabutylammonium bromide (TBAB) as the benign reaction medium. The sensitivity ofLtowards different metal-ions was investigated, and a comprehensive, logica ...

2020

Cyclometalated Ir(III) complexes as tuneable multiband light sources for optical multisensor systems: Feasibility study

Anastasia Gitlina

Development of novel analytical devices complying with modern requirements of simplicity and cost-effectiveness is an important task. Multisensor systems based on various types of chemical sensors are promising tools in this respect. Herein the development ...

2020

Accelerated Discovery of Metal-Organic Frameworks (MOFs) For Energy Related Applications

Arunraj Chidambaram

Metal-Organic Frameworks (MOFs) are an emerging class of materials that consist of metal ions which are linked with organic ligands via coordination bonds to form extended networks. MOF structures consists predominantly of open voids which makes them among ...

EPFL2020

Transport of zinc ions in the hyporheic zone: Experiments and simulations

David Andrew Barry

Large amounts of toxic metals are discharged into rivers and lakes, but little is known about the factors that drive the adsorption and transformation of these metals in the hyporheic zone and the exchange flux across the sediment-water interface. To bette ...

2020

Metal organic frameworks and methods for using thereof

Paul Joseph Dyson, Berend Smit, Fatmah Ebrahim, Serhii Shyshkanov, Kyriakos Stylianou, Ngoc Tú Nguyên

The invention features metal-organic frameworks (MOFs) having a crystalline lattice comprising metallic nodes and organic ligands, wherein each organic ligand comprises a Lewis acidic or basic centre bound to N conjugated systems, wherein N is comprised be ...

2020

Synthesis, reactivity, and environmental relevance of uranyl(V) complexes

Radmila Faizova

Knowledge of fundamental chemical properties of all environmentally relevant uranium species is essential to understand environmental uranium mobility and develop novel remediation strate-gies. A myriad of uranium(VI) and uranium(IV) compounds has been stu ...

EPFL2020

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Color-tunable emitter material

Berend Smit, Fatmah Ebrahim, Christopher Patrick Ireland

2021

Computer Simulation of the Surface of Aqueous Ionic and Surfactant Solutions

Mária Lbadaoui-Darvas

AMER CHEMICAL SOC2022

The influence of chemical composition, aerosol acidity, and metal dissolution on the oxidative potential of fine particulate matter and redox potential of the lung lining fluid

Athanasios Nenes, Andrea Mario Arangio

PERGAMON-ELSEVIER SCIENCE LTD2021