Magnetic and electrostatic effects on the polymerization of water-soluble monomers
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Bis-1,3(N,N,N-trimethylammonium)-2-propylmethacrylate dichloride (di-M) and bis-1,3(N,N,N-trimethylammonium)-2-propylacrylate dichloride (di-A), two new double-charged monomers, were the subject of the research reported in this thesis. These monomers provi ...
The radical polymerization of bis-1,3(N,N,N-trimethylammonium)-2-propylmethacrylate dichloride revealed non-ideality with 0.59 and 4.4 for the reaction orders of the initiator and monomer concentration, respectively. Further, autoacceleration was observed ...
Hydrogels are cross-linked, water-swollen polymer networks. Hydrogels with high mechanical and viscous dissipation properties are of great interest for mechanically control drug release systems. Since hydrogels are 3D polymer network with high amount of wa ...
Protein-polymer conjugates are widely used in biotechnology and medicine, and non-toxic polymers for bioconjugation would be advantageous for these applications. Herein, we reported the toxicity of polymers synthesized by two commonly employed controlled r ...
With an annual worldwide production well in excess of 100 million metric tons, synthetic polymers constitute a significant part of the modern chemical process industry. Polymer reactors - operated in continuous, batch, or semibatch mode - are therefore imp ...
Previously we reported emulsion polymerization of propylene sulfide with Pluronic F127 as an emulsifier, yielding nanoparticles (NPs) in the 25 nm size range. Immunologically functional NPs were prepared by adding an antigen Pluronic conjugate to the polym ...
In this project we target a desired viscoelastic properties of PDMS for the application of thin wall membrane uses as a container to support soft test sample biomaterials during mechanical compression tests. The biocompatible PDMS membrane is produced by a ...
The pH-induced swelling and collapse of surface-tethered, weak polyelectrolyte brushes is of interest for the development of actuators or to allow pH controlled transport or adsorption. This contribution discusses results of an extensive series of quartz c ...
The BaylisHillman reaction provides a protective-group-free strategy to heterobifunctional polyesters, which can be further modified via various post-polymerization modification reactions. This contribution explores the BaylisHillman polymerization of 1,3- ...
The limit of applicability of the monomer-enhanced mechanism as dominant mechanism ruling the initiation process of the polymerization of acrylamide (AM) initiated with potassium persulfate (K2S2O8) has been determined The kinetics and mechanisms for radic ...
Universidad Nacional del Sur y Consejo Nacional de Investigaciones Científicas y Técnicas2010
