Publications associées à The Use of Passive Samplers to Reveal Industrial and Agricultural Pollution Trends in Swiss Rivers

Process-Induced Structures of Injection-Molded High-Density Polyethylene-Combining X-ray Scattering and Finite Element Modeling

The success of plastics heavily relies on fast melt processing methods used for large-scale industrial manufacturing, including injection molding. The hierarchical structure of the solid polymer depends on material selection combined with processing condit ...

Amer Chemical Soc2024

Spatiotemporal Dynamics of Flow and Hydrochemistry in Drainage Networks

Izabela Bujak-Ozga

Despite their high ecological value, non-perennial streams have received less attention than their perennial counterparts. This doctoral thesis addresses this disparity by advancing knowledge on the dynamics of the drainage density and hydrologic processes ...

EPFL2024

Scanning Small-Angle X-ray Scattering of Injection-Molded Polymers: Anisotropic Structure and Mechanical Properties of Low-Density Polyethylene

Marianne Liebi, Manuel Guizar Sicairos

Injection molding is known to create a layered anisotropicmorphologyacross the sample thickness due to varying shear and cooling ratesduring the manufacturing process. In this study, scanning small-angleX-ray scattering was used to visualize and quantify t ...

AMER CHEMICAL SOC2023

Quantified Effects of Multiple Parameters on Inputs and Potential Sources of Microplastics from a Typical River Flowing into the Sea

Florian Frédéric Vincent Breider, Yang Liu, Wenxin Liu

As an important connection of terrestrial and marine ecosystems, rivers input multitudinous (micro)plastics into the oceans. However, comparisons of field and estimated riverine inputs of (micro)plastics and contributions of multiple parameters are limited ...

2022

Water Orientation at the Anatase TiO2 Nanoparticle Interface: A Probe of Surface pKa Values

Arianna Marchioro, Marie Bischoff

The acid-base properties of surfaces significantly influence catalytic and (photo)electrochemical processes. Estimation of acid dissociation constants (pKa values) for colloids is commonly performed through electroanalytical techniques or spectroscopic met ...

AMER CHEMICAL SOC2022

Insights into the Horizontal and Vertical Profiles of Microplastics in a River Emptying into the Sea Affected by Intensive Anthropogenic Activities in Northern China

Florian Frédéric Vincent Breider, Yang Liu, Wenxin Liu

Studies focused only on surface water may underestimate microplastic abundance in aquatic environments. This was the first survey to investigate the vertical (surface, intermediate, and bottom waters) distribution and composition of microplastics (MPs) in ...

2021

Highly Efficient Activation of HCl Dissociation on Au(111) via Rotational Preexcitation

Rainer Beck

The probability for dissociation of molecules on metal surfaces, which often controls the rate of industrially important catalytic processes, can depend strongly on how energy is partitioned in the incident molecule. There are many example systems where th ...

2021

Development and Characterization of Rice Husk and Recycled Polypropylene Composite Filaments for 3D Printing

Véronique Michaud

Nowadays the use of natural fiber composites has gained significant interest due to their low density, high availability, and low cost. The present study explores the development of sustainable 3D printing filaments based on rice husk (RH), an agricultural ...

2021

The Solvent Effect on H2O2 Generation at Room Temperature Ionic Liquid|Water Interface

Hubert Girault

H2O2 is a versatile chemical and can be generated by the oxygen reduction reaction (ORR) in proton donor solution in molecular solvents or room temperature ionic liquids (IL). We investigated this reaction at interfaces formed by eleven hydrophobic ILs and ...

2021

Past and future impacts of climate change on swiss river temperature and discharge investigated with data analysis and numerical modelling

Adrien Michel

This thesis presents the first large-scale assessment of past, present and future impacts of climate change on river temperatures in Switzerland. Water temperature is a crucial factor influencing, among others, the health of aquatic ecosystems, the industr ...

EPFL2021