The spectroscopy and intramolecular vibrational energy redistribution dynamics of HOCl in the v(OH)=6 region, probed by infrared-visible double resonance overtone excitation
Publications associées (37)
Graph Chatbot
Chattez avec Graph Search
Posez n’importe quelle question sur les cours, conférences, exercices, recherches, actualités, etc. de l’EPFL ou essayez les exemples de questions ci-dessous.
AVERTISSEMENT : Le chatbot Graph n'est pas programmé pour fournir des réponses explicites ou catégoriques à vos questions. Il transforme plutôt vos questions en demandes API qui sont distribuées aux différents services informatiques officiellement administrés par l'EPFL. Son but est uniquement de collecter et de recommander des références pertinentes à des contenus que vous pouvez explorer pour vous aider à répondre à vos questions.
We use infrared-optical double resonance excitation, together with laser induced fluorescence (LIF) product detection, to measure rotationally resolved vibrational overtone spectra of hydrogen peroxide at energies up to 4500 cm(-1) above the O-O dissociati ...
We use infrared-visible double resonance overtone excitation to prepare HOCl molecules in single, well-characterized rotational levels of high OH stretching states just above the dissociation threshold on the ground potential energy surface. Combined with ...
Highly resolved vibrational overtone spectra of jet-cooled CH3OH, obtained using selective IRLAPS detection of the vibrational transition, reveal rich vibrational structure that carries detailed information on the intramolecular dynamics. Low-resolution si ...
ack of understanding of the factors that compensate energy defects in near resonant V-V energy transfer constrains our ability to accurately predict resonance widths and, thus, the overall importance of such processes. We have carried out one of the first ...
Slow, large-amplitude chain motions play an important role in determining the macroscopic mechanical properties of polymers. Although such motions have been studied quantitatively by two-dimensional (2D) nuclear: magnetic resonance (NMR) exchange experimen ...
Double-resonance overtone excitation prepares HOCl molecules in single rovibrational states above the unimolecular dissociation threshold in the ground electronic state, Detecting the OH dissociation fragments allows us to observe which reactant states lie ...
This study is concerned with the effects of applying selective pulses to systems with strong 2nd-order scalar couplings in isotropic phase, where different transitions (rs) are assocd. with different transition matrix elements F(rs)+. Two unusual features ...
