Every Thurston map on a -sphere induces a pull-back operation on Jordan curves , where is the postcritical set of f. Here the isotopy class (relative to ) only depends on the isotopy class . We study this operation for Thurston maps with four postcritical points. In this case, a Thurston obstruction for the map f can be seen as a fixed point of the pull-back operation. We show that if a Thurston map f with a hyperbolic orbifold and four postcritical points has a Thurston obstruction, then one can 'blow up' suitable arcs in the underlying -sphere and construct a new Thurston map for which this obstruction is eliminated. We prove that no other obstruction arises and so is realized by a rational map. In particular, this allows for the combinatorial construction of a large class of rational Thurston maps with four postcritical points. We also study the dynamics of the pull-back operation under iteration. We exhibit a subclass of our rational Thurston maps with four postcritical points for which we can give positive answer to the global curve attractor problem.