A chloro-bridged (arene)Ru complex with a polymerizable side chain
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The reactions of arene-metal complexes (arene = p-cymene, benzene or pentamethylcyclopentadienyl, metal = Ru, Rh or Os), including 1,3,5-triaza-7-phosphatricyclo-[3.3.1.1]decanephosphine (pta) and chloro co-ligands, with 9-methylguanine, adenine, and a ser ...
The first solid-state structures of complexed P3N3X6 (X=halogen) are reported for X=Cl. The compounds were obtained from P3N3Cl6 and Ag[Al(OR)4] salts in CH2Cl2/CS2 solution. The very weakly coordinating anion with R=C(CF3)3 led to the salt Ag(P3N3Cl6)2+[A ...
This thesis encompasses work on the coordination chemistry and catalytic activity of half sandwich ruthenium(II)-arene phosphine complexes. The investigation of phosphine dissociation and association reactions of these complexes represents the unifying the ...
Neutral metallamacrocycles with four or ten metal centers were obtained by reaction of [(R3P)PdCl2]2 with 2,3-dihydroxypyridine and derivatives or 2-hydroxynicotinic acid in the presence of base. In all these assemblies, the two O-donor atoms of the ligand ...
Microwave heating was employed to promote arene displacement in reactions of [{(p-cymene)RuCl2}(2)] or [{(1,3,5-C-6,H(3)iPr(3))RuCl2}(2)] with neutral chelate ligands L-L' [L-L': 1,1'-bis(diphenylphosphanyl)methane, 1,1'- bis(diphenylphosphanyl)ferrocene, ...
The tetradentate chelate ligand tris[(1-vinylimidazol-2-yl)methyl]amine (10) was synthesized in five steps from commercially available starting materials. Upon reaction with MCl2 (M = Zn, Cu, Ni, Co) in the presence of NH4PF6, the complexes [M(10)Cl]PF6 (M ...
The synthesis and characterization of a series of cobalt(III) complexes of the general type Co(N2O2)(L-2) are described. The N2O2 Schiff base ligands used are Me-salpn (H2Me-salpn = N,N'-bis(methylsalicylidene)-1,3-propylenediamine) (1-3) and Me-salbn ...
The reaction of [ReBr3(CO)(3)]NEt4 with 3-hydroxy-1,2,3-benzotriazine-4 (3 H) -one in the presence of base gave the ionic rhenium complex [ReBr(C7H4N3O2)(CO)(3)][NEt4] (2) which was crystallographically characterized. A neutral metallamacrocycle 3 was ...
A chiral Lewis acid catalyst was prepd. by mixing 2 equiv of chiral binol-derived organophosphoric acid and 1 equiv of Et2AlCl. In the presence of a catalytic amt. of [I]2Al(III)Cl complex (0.05 equiv), reaction between alpha -isocyanoacetamides and aldehy ...
