Synthesis and structures of bis(tetramethylpiperidino)aluminum halides. X-ray crystal structures of tmp2AlX (X = Cl, Br, I) and [tmp2Al(m-F)]2
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Monoglyme forms a mol. 1:1 adduct with AlBr3 which dissocs. into the ions AlBr2(DME)2+ and AlBr4- in DME, CH2Br2, and CDCl3 as solvents. A hexacoordinated Al center is present in the solid adduct AlBr3.diglyme. The O and Br atoms are arranged in a meridion ...
We report here a new method to obtain electronic spectra of biomolecular ions that are produced in the gas phase by electrospray and cooled to ~10K in a 22-pole ion trap, and we demonstrate this technique by applying it to protonated tryptophan and tyrosin ...
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In situ Fourier transform infrared (FTIR) absorption spectroscopy has been used to determine the fractional depletion of silane in a radio-frequency (ri) glow discharge. The technique used a simple single-pass arrangement and was implemented in a large-are ...
2,2,6,6-Tetramethylpiperidine (tmpH) reacts smoothly with AlX3 (X = Cl, Br, I) and AlH2Cl.2THF to give the addn. compds. tmpH.AlX3 (X = Cl, Br, I) and tmpH.AlH2Cl, resp. These adducts of the secondary amine tmpH are stable and do not undergo intramol. elim ...
