Functionalized 1,1-ethene dithiolates as ligands. Part 5. Synthesis and crystal structure of palladium(II) and platinum(II) complexes with dithioylidene barbituric acid ligands. Molecular structure of a 2,6-diaminopyridine-platinum(II) barbiturate complex
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This thesis is concerned with supramolecular architectures assembled at metal surfaces. The investigations pursued two objectives. On the one hand, the focus was placed on the fabrication of low-dimensional surface-supported network structures by applying ...
[Rh-4 (CO)(6) (mu-Me2PCH2PMe2)(3)], the first example of a hexasubstituted derivative of Rh-4(CO)(12), has a ground state geometry in the solid state and in solution of C-s symmetry with four edge-bridging carbonyls and with each diphosphine ligand bridgin ...
The ligand N,N'-bis[6-carboxy-2-pyridylmethyl]ethylenediamine-N,N'-diacetic acid (H4bpeda) was synthesized using an improved procedure which requires a reduced no. of steps and leads to a higher yield with respect to the published procedure. It was obtaine ...
The silver, copper and gold complexes of tripodal N-heterocyclic carbene (NHC) ligand, 1,1,1-tris[(3-methylimidazol-1-yl-2-ylidene)methyl]ethane were prepd. and characterized. The silver complex of the title ligand, TIMEMe was prepd. by reaction of [H3TIME ...
The unexpected but facile prepn. of the Ag salt of the least coordinating [(RO)3Al-F-Al(OR)3]- anion (R = C(CF3)3) by reaction of Ag[Al(OR)4] with one equiv. of PCl3 is described. The mechanism of the formation of Ag[(RO)3Al-F-Al(OR)3] is explained based o ...
Highly reactive tris-carbene Co(I) complexes [(TIMENaryl)Co]Cl react with org. azides to yield monomeric Co(III) imido complexes (TIMENaryl)Co(NAr') (aryl = mes, xyl; Ar = -C6H4-CH3, -C6H4-OCH3). The cobalt-imido fragment in these complexes is elec ...
Ru(II) and Os(II) p-cymene dichloride complexes with either a pta (1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane) or [pta-Me]Cl ligand which exhibit anticancer activity were prepd. and characterized by 1H and 31P NMR spectroscopy and mass spectrometry. Thr ...
We identify a class of covalent functionalizations that preserve or control the conductance of single-walled metallic carbon nanotubes. [2+1] cycloadditions can induce bond cleaving between adjacent sidewall carbons, recovering in the process the sp(2) hyb ...
A series of trans-platinum(IV) complexes with functionalized aromatic carboxylate ligands, cis,cis,trans-Pt(NH3)2Cl2(CO2C6H4R)2 (R = H (3), p-vinyl (4), p-methoxy (5), p-iodo (6), ...