From weakly coordinating to non-coordinating anions? A simple preparation of the silver salt of the least coordinating anion and its application to determine the ground state structure of the Ag(η2-P4)2+ cation
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The excited state dynamics of silver atoms embedded in helium nanodroplets have been investigated by a variety of spectroscopic techniques. The experiments reveal that 5p 2P1/2 ← 5s 2S1/2 excitation of embedded silver atoms results almost exclusively in th ...
The first solid-state structures of complexed P3N3X6 (X=halogen) are reported for X=Cl. The compounds were obtained from P3N3Cl6 and Ag[Al(OR)4] salts in CH2Cl2/CS2 solution. The very weakly coordinating anion with R=C(CF3)3 led to the salt Ag(P3N3Cl6)2+[A ...
The betain-like carbodiphosphorane CS2 adduct S2CC(PPh3)2 (1) reacts with Ag(I) salts which contain weakly coordinating anions such as [BF4]- or [Al{OC(CF3)3}4]- to produce the cluster compounds [Ag6{S2CC(PPh3)2}4][BF4]6 (2) and [Ag4{S2CC(PPh3)2}4][Al{OC(C ...
Mu-33, a new layered aluminophosphate with an Al/P ratio of 0.66, was obtained from a quasi non-aqueous synthesis in which tert-butylformamide (tBF) was the main solvent and only limited amounts of water were present. During the synthesis, tBF decomposed a ...
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