Electrochemical properties of Ti/SnO2-Sb2O5 electrodes prepared by the spray pyrolysis technique
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In the first part of this paper, IrO2 electrodes produced by thermal decomposition of H2IrCl6 precursor were manufactured using the spin coating deposition technique, where centrifugal forces spread the precursor solution with simultaneous evaporation of t ...
Dimensionally Stable Anodes (DSA®) are electrodes composed of a metal support and an oxide coating (catalyst). Particularly in this thesis, the Ti/IrO2 electrode was used for the study of the fraction of the surface which participates effectively in the in ...
The electrochemical oxidation of 3,4-(methylenedioxy)phenylmethanol (piperonyl alcohol) was characterized by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). Two electrochemical oxidation signals were found for piperonyl alcohol. T ...
The subject of this work is the study of the electrochemical promotion of catalysis (EPOC), also called non-Faradaic electrochemical modification of catalytic activity (NEMCA). In this phenomenon, application of small currents or potentials on catalysts in ...
This paper deals with the electrochem. reactivity of B doped diamond (BDD) electrodes. A comparative study was carried out to show the influence of the presence of graphitic micro-domains upon the surface of these films. Those graphitic domains are sometim ...
Progress in recent years in the field of electrochromic displays based on viologen modified high-surface area TiO2 electrodes (Vio2+/TiO2) has moved the technol. towards commercialization. Viologen mols. (Vio2+), derivatized with phosphonic acid attachment ...
Three substituted-pyridyl functionalized bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) derivatives 1-3 and their corresponding Ni(II) and Co(II) complexes have been synthesized and characterized. Their electrochemical properties in CH2Cl2 solution have ...
A fully conjugated unsymmetrical dimeric squaraine dye was synthesized. The synthetic key step for this dye, a selective Knoevenagel type condensation of end groups to the core moiety, allows the incorporation of a carboxylic acid function essentially for ...
Cyclic voltammetry is used to study the role of 5,10,15,20-tetraphenyl-21H,23H-porphine (H2TPP) in the reduction of molecular oxygen by decamethylferrocene (DMFc) at the polarized water|1,2-dichloroethane (DCE) interface. It is shown that this rather slow ...
A novel two-step method was developed to prep. gold nanoparticles on boron-doped diamond (BDD) electrode. It consisted of sputter deposition of max. 15 equiv monolayers of gold, followed by a heat treatment at 400-600 Deg in air. The as-sputtered gold depo ...